质子交换膜燃料电池用炭纸的研制和其性能表征.pdfVIP

S7 质子交换膜燃料电池用炭纸的研制及其性能表征 张明瑜 1,2 苏哲安 1 谢志勇 1 黄启忠 1 (1 中南大学粉末冶金国家重点实验室，湖南长沙 410083 2 中南大学冶金科学与工程学院，湖南长沙 410083) 摘要：质子交换膜燃料电池(PEMFC)据信是汽车用石油能源的潜在替代者之一。炭纸是一种二维 的炭/炭复合材料。利用干法新技术制备的炭纸预制体，提出了通过树脂浸渍炭化后进行化学气 相沉积制备 PEMFC 用炭纸的复合新技术。详细研究了炭纸的理化性能和燃料电池性能。结果表 明炭纸的导电性能优于东丽T060 炭纸，并且在干燥运行状态时燃料电池性能表现优于东丽 T060 炭纸而在高电流密度和高湿度环境下燃料电池性能稍低于东丽 T060 炭纸。提高燃料电池炭纸性 能并降低其制造成本、批量生产仍需要进一步研究。 关键词：质子交换膜燃料电池(PEMFC) ；炭纸；制备；性能 Preparation and characteristics of carbon paper for PEMFC 1,2 1 1 1 Mingyu ZHANG , Zhean SU , Zhiyong XIE , Qizhong (State Key Laboratory for Powder Metallurgy, Central South University, Changsha 410083 China; School of Metallurgical Science and Engineering, Central South University, Changsha 410083 China) Abstract: PEMFC (proton exchange membrane fuel cell) is believed to be a potential energy for automobiles instead of oil in future. Carbon paper is a kind of 2D carbon/carbon composites. Taken advantage of the new dry-made carbon paper preform, a novel technique for preparation of carbon paper by impregnation and chemical vapor deposition was proposed. The properties of this carbon paper were investigated in detail. The results show that the conducting properties is over that of Toray T060 carbon paper and comparing with the performance of fuel cell installed with Toray T060 carbon paper ，performance of fuel cell is excellent under dry operating conditions but show lower performance deficit at high current densities and under high wet operating conditions. At present, small scale production of carbon paper have been provided for