宝珠砂在酯硬化碱性酚醛树脂自硬砂应用.pdfVIP

2010 中国铸造活动周论文集 宝珠砂在酯硬化碱性酚醛树脂自硬砂中的应用 李伟华，董选普，吴香清 （华中科技大学材料成形与模具技术国家重点实验室，湖北 武汉 430074） 摘要：本文通过扫描电镜观察了宝珠砂颗粒形状与表面状态，研究了宝珠砂在酯硬化碱性酚醛树脂自硬砂 中的常温强度，溃散性能和再生性能，并与都昌砂对比，结果表明：宝珠砂颗粒圆整和表面存在微观孔洞， 提高了酯硬化碱性酚醛树脂自硬砂常温强度和再生性能，树脂加入量减少 55%，再生脱模率提高 10%，溃 散性能良好，为宝珠砂在铸钢生产中的应用提供了指导和参考。 关键词：宝珠砂；碱性酚醛树脂自硬砂；强度；溃散性；再生性 Application of Ceramacore in Ester Cured Alkali Phenol Resin Sand LI Wei-hua, DONGD Xuan-pu, WU Xiang-qing （State Key Laboratory of Material Forming and Die Mould Technology, Huazhong University of Science and Technology, Wuhan 430074, Hubei, China ） Abstract: In this paper, the shape and surface of the Ceramacore particle was observed by means of SEM, and normal strength performance, collapsibility and reclamation property of Ceramacore in ester cured alkali phenol resin sand were researched, and compared with Duchang sand, the results showed: Ceramacore particle was roundness and there were many micro holes in the surface, and these features improved the normal strength performance and reclamation property, and the quantity of phenol resin was reduced 55%, and the stripping ratio was improved 10%, and the collapsibility was well, and these provided guidances and references for application of Ceramacore in cast steel production. Key words: Ceramacore; ester cured alkali phenol resin sand; strength; collapsibility; reclamation 由于酯硬化碱性酚醛树脂自硬砂环保方面的优势及独特的性能，近年来已被国内诸多铸钢厂采用，如 二重、广重、宏钢、南机等。目前该工艺在高锰钢、大型或重型铸钢及不锈钢等铸件的生产中已被广泛采 用并取得了很好的使用效果[1～3]。由于硅砂热膨胀系数比较大，而且会因相变而产生膨胀，同时容易与铁 的氧化物起作用，形成粘砂缺陷，而锆英砂耐火度高，导热性和热膨胀性小，高温状态下表现为中性，克 服了硅砂的缺陷[4]，但由于锆英砂价格昂贵，多用做大型铸钢件厚壁处和各种合金钢铸件的面砂。美国 Carb Ceramics 公司于上个世纪 80 年代研制了一种人工烧制的陶瓷球形颗粒，商品名为 Ceramacore，中文俗称 宝珠砂，是以优质铝矾土为原料，经重熔冶炼再喷吹成球形，球度圆度高，耐火度高，强度高，流动性和 透气性好，是精密铸造、覆膜砂、自硬砂的新型