PPE%2fTAIC混合物的相行为与固化行为.pdfVIP

PPE/TAIC 混合物的相行为和固化行为 田 勇, 皮丕辉, 文秀芳, 程 江,杨卓如 华南理工大学化工与能源学院，广东 广州 510640 ） （ 摘要： 低分子量PPE/TAIC 混合物具有最高上临界温度行为，玻璃化转变温度(T)线和浊点曲线在PPE 的 g 含量约为50 wt %时相交。通过带有控温装置的显微镜、红外和DSC 来研究PPE/TAIC 混合物的相行为和 固化行为。采用原子力显微镜研究PPE/TAIC 混合物固化材料的相态。研究结果表明，随着PPE/TAIC 混合 物中PPE 含量的增加，分散相PPE 颗粒的大小明显地增加，另外混合物的热稳定性也随之增强。固化后的 PPE/TAIC 体系具有良好的耐化学药品性和耐热性。 关键词： 聚苯醚；三烯丙基异氰酸酯；相行为；固化行为 中图分类号：TQ326.53 文献标识码：A THE PHASE BEHAVIOR AND CURE BEHAVIOR OF POLY (2, 6 – DIMETHYL-1, 4-PHENYLENE ETHER) / TRIALLYLISOCYANURATE BLENDS TIAN Yong , PI Pi-hui , WENG Xiu-fang , CHENG Jiang ,YANG Zhuo-ru (The school of Chemical and Energy Engineering, South China University of Technology, Guangzhou 510640) Abstract: The low molar mass PPE/TAIC blends were shown to have the upper critical solution temperature (UCST) type phase behavior, and cloud point curves intersect the glass transition-composition lines at a PPE content of about 50 wt %. Phase behavior and cure behavior were investigated by different techniques: Light Transmission measurements, Fourier-transform Infrared Spectrometer, and Different Scanning Calorimeter. The cured morphology of the PPE/TAIC blends was studied by atom force microscope. With increasing PPE content for PPE/TAIC blends, the diameter of the dispersed PPE particles has a significant increase, and the thermal stability of the blends is also increased. The cured PPE/TAIC systems exhibit good chemical resistance and thermal stability. Key words: poly (2,6-dimethy-1,4-phenylene ether); triallylisocyanurate; phase behavior; cure behavior 聚苯醚(PPE) 因具有低介电常数、高玻璃化温度、良好的尺寸稳定性和耐冲击性等特点,而 被广泛地应用于先进复合材料的制造中[1-3] 。纯PPE 的熔化处理(300-350