不同价态铁元素对牛粪秸秆厌氧混合发酵产氢效能影响.pdfVIP

EnhancedsimultaneousCongoreddecolorizationand bioelectricitygenerationinmicrobialfuelcellbyhumicacid JianSunYongyouHuQianXuYa-pingZhangBinHouSizheLi MinistryofEducationKeyLaboratoryofPollutionControlandEcologicalRemediationfor IndustrialAgglomerationArea,CollegeofEnvironmentalScienceandEngineering, SouthChinaUniversityofTechnology,Guangzhou,510006,China StateKeyLabofPulpandPaperEngineering,CollegeofLightIndustryandFoodScience, SouthChinaUniversityofTechnology,Guangzhou,510640,China Abstract:Efficientelectrontransferamongmicrobes,azodyeandanodeisakey factorforsimultaneousazodyedecolorizationandelectricitygenerationinmicrobial fuelcell(MFC).Inthisstudy,naturalmediator-humicacid(HA)wasintroduced to enhancesuchextracellularelectrontransfer.TheresultsshowedthattheadditionofHA greatlyenhancedazodyedecolorizationandelectricitygenerationsimultaneously. Additionof5g/LHAresultedin45％ increaseinmaximumpowerdensityandalmost 300％ increaseindecolorizationrateofCongored.Thedataofreductioninanode polarizationresistanceandacceleratedreductivedecolorizationofCongoredinthe presenceofHAindicatedthatHAisparticularlyeffectiveinfacilitateelectronstransfer frommicrobestoazodyeandmicrobestoanode.Denaturinggradientgel electrophoresisanddirect16SribosomalDNAgenenucleotidesequencingrevealedthat theadditionofHAdidnotchangethemicrobialcommunitycompositionintheMFC butresultinthegrowthofsomedominantbacterialspecies.Thesespeciesweremost likelytoutilizeHAasmediatortoacceleratetherateofelectronstransferinvolvedin bothelectricitygenerationandazodyedecolorization. 不同价态铁元素对牛粪秸秆厌氧混合发酵产氢效能的影响 勾晨哗 姜宗姗廉静*郭建博 河北科技大学环境科学与工程学院，石家庄050018 摘要：氢气作为一种清洁、高效、无污染的可再生能源，被广泛的应用于多 个行业。在生物制氢的诸多方法中，厌氧发酵可利用多种有机废物产氢，由于我 国是农业大国，农业废弃物种类多、数量大，且大部分农业废弃物如秸秆、禽畜 粪便等不能得到很好的利用，造成了巨大的资源浪费并带来了严重的生态破坏和 环境污染问题，因此，利用作为废弃物的牛粪与秸秆发酵产氢既能减废又可以产 能，是一种经济、环保、绿色的制氢方法。目前有研究表明在产氢微生物的体 内，铁元素是电子传递的载体