有序介孔碳_石墨烯复合材料的制备及其对银纳米粒子吸附性能的研究.pdfVIP

·18· 刘攀博等，有序介孔碳-石墨烯复合材料的制备及其对银纳米粒子吸附性能的研究 Vol． 35，No． 2 ，2013 有序介孔碳-石墨烯复合材料的制备及其对 银纳米粒子吸附性能的研究 刘攀博，黄 英 （西北工业大学 理学院应用化学系，空间应用物理与化学教育部重点实验室，陕西西安 710129） 摘要：以溶剂挥发诱导有机-有机自组装法制备了有序介孔碳-石墨烯（OMC-RGO）复合材料。结果表明：当焙烧温度为 800℃时，所得的OMC-RGO复合材料与OMC相比，其电导率从0.76S/m增加到32.5S/m，提高到42.8倍；但BET比表面积和孔 2 3 2 3 容分别从670m/g和0.40cm/g下降到361m/g和0.23cm/g，降低的比率分别为46.1％和42.5％。随后，我们以OMC-RGO为载 体，通过物理吸附制备了有序介孔碳-石墨烯-银纳米粒子（OMC-RGO-Ag）复合材料。结果表明：OMC-RGO表面上Ag纳米 粒子的粒径在20～40nm之间；且OMC与RGO复合后，RGO表面上的含氧官能团有利于吸附较多的Ag纳米粒子。 关键词：有序介孔碳；石墨烯；银纳米粒子；复合材料 中图分类号：TQ322.99 文献标识码：A 文章编号：1001-0017（2013）02-0018-04 Preparation of Ordered Mesoporous Carbon-Reduced Graphene Oxide Composites and the Research on Adsorption of Ag Nanoparticles LIU Pan-bo and HUANG Ying （Key Laboratory of Space Applied Physics and Chemistry, Ministry of Education, Northwestern Polytechnical University, Xian 710129, China） Abstract ：The ordered mesoporous carbon -reduced graphene oxide (OMC -RGO) composites were prepared through organic -organic self - assembly method. The results showed that the conductivity of OMC-RGO increased from 0.76S/m to 32.5S/m, which was about 23-fold in comparison 2 3 2 3 with OMC, but the BET surface area and pore volume of OMC-RGO (361m /g, 0.23cm /g) were lower than OMC (670m /g, 0.40cm /g) by calcination at 800℃. Then the OMC-RGO-Ag nanocomposites were prepared by directly adsorption of Ag nanoparticles with using OMC-RGO as matrix, the results showed that the average diameter of Ag on the surface of RGO-OMC was between 20 and 40 nm, the presence of oxygen-containing groups on the surface of RGO was favorable to adsorb more Ag nanoparticles. Key words ：Ordered mesopo