环氧树脂电子束固化微观结构及其影响因素.pdfVIP

2007 8 August 2007 33 8 Journal of Beijing Univers ity of Aeronautics and Astronautics Vo.l 33 No8 李玉彬 张佐光 孙志杰 杨嘉陵 ( , 00083) ( , 00083) : 采用扫描电镜对不同固化时间下电子束固化环氧树 的微观结构进行观察 和分析, 探讨其形成过程, 并研究了树 分子结构相对分子质量树 体系组分及辐射条件对 微观结构的影响. 实验结果表明, 环氧树 经电子束固化后形成片层结构, 树 分子结构和分 子量对其固化微结构的影响不大; 不同结构分子量的环氧树 电子束固化过程中均会经历预 聚体结构 圆片网络 圆片形成 圆片增长的生长过程, 故其微观结构都呈现圆片状形貌; 随 着辐射剂量的增加, 圆片逐渐增大; 存在最佳引发剂用量, 使圆片尺寸达到最小. : 电子束; 辐射固化; 环氧树 ; 微观结构 : TB 332 : A : 00 5965( 2007) M icrostructure and a ffecting facto rs of epoxy res in cured by e lectron beam rad iation LiYub in Zhang Zuoguang Sun Zh ijie ( School ofMaterials Science and Engineering, Beijing U niversity of Aeronautics and Astronautics, Beijing 00083, China) Yang Jialing ( School of Aeronautic Science and Engineering, Beijing University ofA eronautics andA stronautics, Beijing 00083, China) Abstract: A scann ing electron m icroscope ( SEM) w as used to observe the m icrostructures of cured sam ples after different cure tmi e. The formation mechan ism ofm icrostructurew as analyzed. The effects ofmolecu lar structure and molecu larw eight of epoxy resin, resin component, and rad iation condition on them icrostruc ture w ere also researched. The resu lts show that the cure zone of epoxy resin consists of lam ellae, and the res in molecu lar structure and weight have little effect on the curedm icrostructure. U nder the electron beam rad ia tion, epoxy resinsw ith d ifferent structures ormolecularw eights all form prepolym er at first, then the prepoly