磷酸亚铁锂核壳结构材料的制备和电化学性能.pdfVIP

23 1 Vol.23 No.1 2 0 0 9 2 CHINESE JOURNAL OF MATERIALS RESEARCH February 2 0 0 9 (Æ () 110016) //, . , , . , , . , , , TB321 1005-3093(2009)01-0022-05 Synthesis and electrochemical property of LiFePO4 with core-shell structures LIU Shuhe WEN Lei BAI Suo∗ LI Feng WANG Zuoming (Shenyang National Laboratory for Materials Science, Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016) Manuscript received March 5, 2008; in revised form May 12, 2008. * To whom correspondence should be addressed, Tel:(024 E–mail:sbai@imr.ac.cn ABSTRACT Two types of core-shell structured cathode materials-pyrolytic carbon(PyC)/LiFePO4 and carbon nanofiber(CNF)/LiFePO4 were synthesized by fluidized bed chemical vapor deposition method and their electrochemical properties were explored. The PyC or CNF coating can effectively reduce the resistivity of LiFePO4 , and greatly improved its charge-discharge capacity and cyclability. Compared with PyC, the one dimensional structure and excellent mechanical performance of CNF make it more suitable as the conductive additive of LiFePO4 . KEY WORDS inorganic non-metallic materials, LiFePO4 , fluidized-bed, electrochemical property , LiCoO , 2 LiNiO LiMn O , (LiFePO ) Æ. , 2 2 4 4 . , , LiFePO4 , , . , . 1997 , LiFePO4 , (