一种煤与两种城市污水污泥混合热解的热重分析.pdfVIP

第39卷 第1期 燃摇 料摇 化摇 学摇 学摇 报 Vol.39 No.1 2011年1月 Journal of Fuel Chemistry and Technology Jan. 2011 文章编号:0253鄄2409(2011)01鄄0008鄄06 一种煤与两种城市污水污泥混合热解的热重分析 1,2 1 1 刘秀如 ,吕清刚 ,矫维红 (1. 中国科学院工程热物理研究所,北京摇 100190;2. 中国科学院研究生院,北京摇 100049) 摘摇 要:采用热重分析法对一种煤和两种城市污水污泥(S1和S2)及其混合物进行了热解实验研究,揭示了煤和污泥在氮气 中的热解特性及污泥对煤热解特性的影响。 煤和污泥的热解特性参数不同,主要表现在总失重率、失重速率及挥发分析出温 度区间等。 煤与污泥S1混合有助于增加样品的热解总失重率,提高失重速率;污泥S1与煤的挥发分析出区间部分重合,污 泥灰中含的无机物对煤的热解起到催化效果;煤和S2污泥混合后热解反应过程中无明显相互作用;煤与城市污水污泥混合 物的相互作用与样品特性和混合比例有关。 关键词:煤;污泥;热解;热重分析;催化 中图分类号:X705摇 摇 文献标识码:A Thermogravimetric analysis of co鄄pyrolysis of coal with different municipal sewage sludge 1,2 1 1 LIU Xiu鄄ru ,L譈 Qing鄄gang ,JIAO Wei鄄hong (1.Institute of Engineering Thermophysics,ChineseAcademy of Sciences,Beijing摇 100190,China; 2.Graduate University of ChineseAcademy of Sciences,Beijing摇 100049,China) Abstract:Pyrolysis experiments of coal,two kinds of municipal sewage sludge (S1and S2) and the mixture were carried out in nitrogen atmosphere by thermogravimetric analysis. The pyrolysis characteristics of the coal and the municipal sewage sludge samples and the effects of sewage sludge on coal pyrolysis were studied. The coal and sewage sludge have different pyrolysis characteristicsparametersin aspects of total weight loss,weight lossrateandvolatilereleasetemperaturerange. Appropriatemixingof S1andcoalisbeneficialtotheincreasein the total weight loss and weight loss rate of pyrolysis reaction. There is partial overlap between the volatile release ranges of S1 and the coal. The inorganic matter in sewage sludge ash has catalytic effect on coal pyrolysis.