改性沸石预涂层改善超滤膜通量研究.pdfVIP

第 21卷 第 12期 中国给 水排 水 Vo.l 21 No. 12 2005年 12月 CH INA WATER WASTEWATER Dec. 2005 汪 力, 董秉直, 夏丽华, 高乃云 (同济大学 污染控制与资源化研究国家重点试验 , 上海 200092) : 采用改性粉末沸石对超滤膜表面进行预涂层, 研究了预涂层工艺对改善膜通量的作 用与机理, 结果表明: 沸石经酸法改性后, 比表面积增加, 表面负电性降低, 是合适的涂层物质改 性粉末沸石与超滤膜联用对有机物的去除具有协同作用, 在改性沸石涂层量为 300 mg /L的条件 下, 对 COD 的去除率为 29. 6%, 对UV 的去除率为 21. 8% , 比原水经膜直接过滤有较大程度提 Mn 254 高沸石预涂层能够使膜表面和膜孔内的有机物浓度降低, 因而维持较高膜通量, 有效防止了膜污 染改性沸石预涂层主要增加了对分子质量 3 000 u有机物的去除率, 这对提高膜通量的贡献较 大表面呈弱负电性的改性沸石能够形成结构松散孔隙较大的滤饼层, 反冲洗时容易被冲洗掉, 膜通量能够得到很好恢复 : 改性粉末沸石; 预涂层; 超滤膜; 膜通量 : TU991. 2 : A : 1000 4602( 2005) 12 0005 05 Modified Powdered Zeolite Pre-coating Process for Improvement of Ultra-filtrationM embrane Flux WANG L,i DONG Bing zhi, XIA Li hua, GAO Nai yun ( StateK ey L a b of P ollu tion Control and R esource Reuse, Tongj i Un iv ers ity, Shang ha i 200092, Ch ina) Abstract: Modified powdered zeolite was pre coated on the ultrafiltration membrane. The effect and mechanism of zeolite pre coating process on mi proving ultrafiltration membrane flux were studied. The result show s that the modified zeolite is increased in specific surface area and decreased in surface negative charge, and is a suitable pre coating materia.l The combined use of modified powdered zeolite and ultrafiltration membrane has synergistic effect on organics remova.l Under the pre coating dosage of 300mg/L, the removal rate of CODM n and UV254 is 29. 6% and 21. 8% respectively, much more than that of direct filtration of ultrafiltration membrane. Themodified zeolite pre coating process can mi prove membrane flux and prevent effectively