一种新型固体碱高稳定性介孔CaO_ZrO_2的制备及性能.pdf

·1626 · CHEMICAL INDUSTRY AND ENGINEERING PROGRESS 2007 26 11 CaO-ZrO 2 1, 2 1 1 1 1 1 030001 2 100039 -CaO-ZrO2 XRD TEM 700 CO -TPD 2 3 CaO 120 h CaO-ZrO2 TQ 426.94 A 100066132007 Preparation and property of mesoporous CaO -ZrO solid base with 2 high activity and stability 1,2 1 1 1 1 LIU Shuigang LI Junping ZHAO Ning WEI Wei SUN Yuhan 1 State Key Laboratory of Coal Conversion Institute of Coal Chemistry Chinese Academy of Sciences 2 Taiyuan 030001ShanxiChina Graduate School of Chinese Academy of Sciences Beijing 100039 China Abstract A new solid base CaO-ZrO2 nanocomposite was prepared via an appropriate sol-gel process. It was found that such nanostructure greatly improved the basic strength and durability of the solid base catalyst. Temperature programmed desorption of CO (CO -TPD) and X-ray photoelectron spectroscopy 2 2 (XPS) demonstrated that both weak and strong basic sites coexisted on the surface of CaO-ZrO2 nanocomposite. At the same time the mesoporous CaO-ZrO2 nanocomposite showed high thermal stabilitysince X-ray diffraction (XRD)transmission electron microscopy (TEM) proved that the mesoporous network of this material was preserved well ev