稻秆的热解特性及热解模型的建立.docVIP

Study on pyrolysis for rice straw behavior and model construction of pyrolysis Zhaochuang Jiangenchen※ Chenliangguang Xiongleiming (Engineering college in south China Agricural University ,guangzhou, China，510642) Email：※ecjiang@ ，zhao020057@126.com , Abstract: By using STA449C Jupiter? thermogravimetric apparatus, effect of the heating rate and ratio of adding catalyst for rice straw were studied, which showed that as the heating rates increased, weight loss was little, weight loss rate changed heavily,; after adding catalyst, retention rate increased ( yield of carbon rised), activation energy of pyrolysis lowered,as ratio of adding catalyst increased, activation energy of pyrolysis rised, activation energy lowered , then rised .By Malek method , it could be determined that pyrolysis process of rice straw accorded with the random nucleation and later growth. By estimating trial data, pyrolysis reaction series of rice straw was 0.4, pyrolysis reaction series of rice straw plus 10% catalyst was 0.46, pyrolysis reaction series of rice straw plus 15% catalyst was 0.42. By estimating pyrolytic reaction of rice straw, which were 184.07 kJ/mol, 158.70 kJ/mol and 172.60 kJ/mol, and in accord with Coats and Redfern method . Correctness and applicability of the mechanism model were further confirmed by pyrolysis of rice straw segment model calculation, reliability of the mechanism model was vetified by Kinetics software. Key words: pyrolysis,catalyst, mechanism,kinetic,pyrolysis parameters, 稻秆的热解特性及热解模型建立 赵创 蒋恩臣※ 陈亮广 熊磊明 华南农业大学工程学院，广州 ，中国，510642 Email：※ecjiang@，zhao020057@126.com , 摘要：该文采用耐驰STA 449C Jupiter?同步热重分析仪，研究了升温速率和添加催化剂比例对稻秆的的热解过程的影响。结果表明，随着升温速率的增大，失重量变化不明显，但失重速率变化显著；添加催化剂后，热解的残留率增大，即焦炭产率上升，随着催化剂添加量的增加，活化能先降低后增加。用Malek法确定其热解机理模型为随机成核和随后成长，通过拟合的方法得到的主热解阶段活化能与Coats Redfern 法的计算结果相符 kJ/mol、158.70 kJ/mol和172.60 kJ/mol。通过稻秆热解的分段模型1引言 对化石燃料急剧的需求和环境问题的担忧，促使人们对可再生能源之一的生物质能广泛关注，其在整个能源结构中占有重要地位。可以将生物质通过不同的方式和机理转化成生物质燃料，例如，H，CH，乙醇或者气化燃气等。燃气可以用作动力装置燃料，输出电力或动