原位聚合改性GF_SAN的界面模型及增韧机理研究.pdfVIP

理论与研究 Vol.36 No.7 (Sum.195) July 2008 文章编号：1005-3360（2008）07-0024-04 原位聚合改性GF/SAN的界面模型及增韧机理研究 Study on Interfacial Model and Toughening Mechanism of GF/SAN Modified by In-situ Polymerization 1 2 1 1 1 2 1 1 曾 武 ，应继儒 ，刘 斌 ，瞿金平 Zeng wu , Ying Jiru , Liu Bin , Qu jinping - 1. 华南理工大学聚合物成型加工工程教育部重点实验室，广东 广州 510640 2. 湖北工业大学化学与环境工程学院，湖北 武汉 430068 - 1. Key Laboratory of Polymer Processing Engineering of Ministry of Education, South China University of Technology, Guangzhou 510640, China 2. College of Chemical and Environmental Engineering, Hubei University of Technology, Wuhan 430068, China : 采用原位乳液聚合接枝法改善玻璃纤维 （GF）与苯乙烯 - 丙烯腈共聚物（SAN）之间的界面黏结性能。对 GF/SAN 复合材料进行了冲击性能测试和微观结构分析，结果表明：原位聚合改性 GF 与 SAN 之间有良 好的界面黏合力，可以有效地提高 SAN 的韧性。设计了一种新的界面模型，以解析原位聚合改性的 GF 与 SAN界面的微观结构，并解释了GF/SAN复合材料的增韧机理。 Abstract : The in-situ emulsion polymerization technology was adopted to improve the interfacial adhesion between glass fiber (GF) and styrene-acrylonitrile copolymer (SAN). The impact property of GF/SAN composite was tested, and the microstructure of the composite was also analyzed. The results show that: the interfacial adhesion between GF modified by in-situ polymerization and SAN is excellent, modified GF could improve the toughness of SAN efficiently. An interfacial model was designed to explain the interfacial microstructure between modified GF and SAN. The toughening mechanism of GF