不同细度紫茎泽兰水凝胶的溶胀动力学的研究.docVIP

不同细度紫茎泽兰水凝胶的溶胀动力学研究 刘其星，高 欣*，陈克利，张 恒 （昆明理工大学化学工程学院，云南 昆明 650500） 【摘要】以不同细度粉末状紫茎泽兰为原料，对比研究在相同的接枝共聚改性条件下所得不同水凝胶的溶胀行为。结果表明：Ⅰ-1 (Ⅰ-10凝胶的n值均在0.50 ( 1.0范围内，随原料颗粒细度的减小，n值呈下降趋势；且同种凝胶在蒸馏水中的扩散特性指数均大于在生理盐水中的n值，说明在0.020 ~ 0.450mm原料细度内都可用non-Fickian扩散描述，初始原料颗粒细度的变化和溶胀液体介质性质会影响水凝胶产物的溶胀过程。同时，通过Beren-Hopfenberg微分方程描述凝胶吸液值大于60%的溶胀行为，并计算得到相应凝胶扩散常数。不同EA-co-PAA/PAM水凝胶的溶胀行为均满足Schott二级动力学方程，根据平衡吸液量，可得在0.054 ~ 0.075mm原料细度范围内紫茎泽兰水凝胶表现出较优的吸液能力。 【关键词】紫茎泽兰；颗粒细度；水凝胶；溶胀动力学 中图分类号：TQ321 文献标识码：A Swelling Kinetics Study of Hydrogels prepared by the different finesses of Eupatorium Adenophorum LIU Qi-xing，GAO Xin，ZHANG Heng，CHEN Ke-li (Kunming University of Science and Technology, Faculty of Chemical Engineering , Kunming 650500, China) 【Abstract】 In this study the different finesses of the pulverized Eupatorium Adenophorum (EA) was evaluated as potential raw materials for the low-cost but superabsorbent hydrogels whose the swelling behaviors were compared and studied at the same graft-copolymerization condition. The results are shown that the swelling rates and swelling ratios of EA hydrogels increased with decreasing the granule size of pulverized EA and the swelling exponents ‘n’, being in the range of 0.50~1.00, have been found to indicate non-Fickian mechanism at the finesses range of 0.020~0.450mm, and the result of greater ‘n’ values in deionized water than in 0.9%NaCl is indicative of the probability that the medium property influences on gels’ uptake mechanism. Moreover, to obtain better model for above 60% water uptake, the Beren-Hopfenberg differential model was applied, which also enabled to calculate the relaxation constants. Additionally, the gels demonstrated second-order kinetics as confirmed from the linear nature of the plots obtained by fitting the experimental data to Schott equation, thus suggesting that EA hydrogels exhibit comparatively superior swelling capability at the condition of 0.020~0.450mm. 【Key words】 Eupatorium adenophorum; granular fi