木质素炭与纤维素炭对硝基苯吸附性能比较.pdfVIP

木质素炭与纤维素炭对硝基苯的吸附性能比较 李建法，李益民，吴云露，郑梦莹 （绍兴文理学院化学系，浙江 绍兴 312000 ） E-mails: ljf@usx.edu.cn （李建法）；liym@usx.edu.cn （李益民） 摘要：生物炭对污染物的吸附性能取决于其组成和表面特性，二者又与制备生物炭的生 物质原料有关。为了探讨生物质原料对生物炭吸附性能的影响，分别以木质素、纤维素 为原料，在氮气氛中经 400 ºC 和 600 ºC 热解制备生物炭，并与相同条件下制备的木屑 炭比较。元素分析表明，相同热解温度下木屑炭的组成和炭化程度更接近纤维素炭，而 与木质素炭明显不同，表明木质素不是影响生物炭组成的主导因素。木质素炭对硝基苯 的吸附能力与纤维素炭、木屑炭相当，但是由于木质素炭化程度较低，分配作用对吸附 能力的贡献较大，导致硝基苯较易从木质素炭上脱附。 关键词：生物炭; 木质素; 吸附; 硝基苯; 脱附 Comparison of lignin and cellulose biochars as sorbents to nitrobenzene Jianfa Li, Yimin Li, Yunlu Wu, Mengying Zheng (Department of Chemistry, Shaoxing University, Shaoxing, Zhejiang 312000) ABSTRACT: Biochars’ performance as the sorbent to pollutants is dependent on their compositions and surface characteristics, which are then related to the feedstock used for biochar preparation. The objective of this work is to probe the feedstock’s influence on biochar’s sorption property through a comparative study on biochars from lignin, cellulose and wood prepared at 400 ºC and 600 ºC, respectively. Elemental analysis demonstrated that the wood biochar had a composition and carbonization degree close to the cellulose biochar but much different from the lignin biochar prepared at the same temperature. The lignin biochar showed a sorption capacity comparable to both cellulose and wood biochars as the sorbent to nitrobenzene, with a higher partition contribution to the total sorption due to the lower carbonization of lignin, which leads to the easier desorption of nitrobenzene from lignin biochars. Keywords: Biochar; Lignin; Sorption; Nitrobenzene; Desorption 李建法：男（1968—），博士，教授，从事生物炭及污染控制研究； 基金项目：国家自然科学基金（编号）经费资助。 1 1. Introduction