NACE 阴极保护讲座Nov 2006.ppt

* of 109 Effect of Temperature on Polarization log I P o t e n t i a l I@T1 + _ Increased Temperature (T3) Increased Temperature Decreased Temp. (T1) Decreased Temp. Anode Cathode E T1T2T3 I@T2 I@T3 (T2) * of 109 Electrolyte / Electrode Movement An increase in movement between the electrodes and the electrolyte results in a decrease in polarization and increase in current. In stagnant electrolytes the movement decreases, causing an increase in polarization and decrease in current. * of 109 Electrolyte / Electrode Movement P o t e n t i a l I@V1 + _ Increased Movement (V3) Increased Movement Decreased Movement (V1) Decreased Movement Velocity1Velocity2Velocity3 I@V2 I@V3 log I Anode Cathode E (V2) * of 109 Metal Ion Concentration An increase in the metal ion concentration of the anode metal results in an increase in polarization of the anode and a decrease in current. A decrease in anode metal ions causes a decrease in polarization of the anode and an increase in current. * of 109 Metal IonConcentration P o t e n t i a l I@M1 + _ Increased Metal Ion Conc. M1M2M3 I@M2 I@M3 Decreased Metal Ion Conc. log I Anode Cathode E * of 109 Cathodic Reactant Concentration An increase in the concentration of either oxygen or hydrogen ions (cathodic reactants) will decrease polarization of the cathode and increase current. A decrease of cathodic reactants will increase polarization of the cathode and decrease current. * of 109 Oxygen Concentration log I P o t e n t i a l I@O1 + _ Increased Oxygen Concentration Anode Cathode E O1O2O3 I@O2 I@O3 Decreased Oxygen Concentration * of 109 Effect of pH on Cathodic Polarization I@pH1 Decreased pH pH1pH2pH3 I@pH2 I@pH3 Increased pH Remember as pH decreases hydrogen ions (H+) increase log I P o t e n t i a l + _ Anode Cathode E * of 109 Passivity Passivity can be defined as the loss of chemical reactivity: Exhibited by specific metals and alloys under specific environmental conditions Caused by the formation of a surfac