硅烷γ-APS协同稀土镧钝化镀锌钢板的研究.pdfVIP

维普资讯 腐蚀科学与防护技术 Vo1．20NO．5 CORROSION SCIENCEAND PROTECTION TECHNOLOGY Sep．2008 潞5月 硅烷 -APS协同稀土镧钝化镀锌钢板的研究 期 彭天兰，满瑞林 ，徐斌，乔亮杰 中南大学 化学化工学院，长沙410083 摘要：采用 -氨丙基三乙氧基硅烷(-APS)协同稀土镧盐钝化镀锌钢板．通过先在试样表面组装一层 一APS薄膜 ， 再在膜上沉积稀土镧转化膜制得硅烷稀土复合膜．采用电化学交流阻抗 (EIS)、盐雾试验 (NSS)检测复合膜耐腐蚀 性，结果表明，复合膜的耐腐蚀性能优于单一硅烷、稀土转化膜．原子力显微镜检测结果表明复合膜相对于单一硅 烷、稀土转化膜更加均匀，致密．EDS检测表明复合膜主要由N，O，Si，Fe，Zn，La等元素组成，其中复合膜中La元素 相对摩尔百分含量是单一稀土转化膜的4倍．分析试验数据得出硅烷预处理试样有利于稀土镧转化膜沉积，硅烷 与稀土转化膜发生了协同作用，增强了复合膜耐腐蚀性能．初步探讨了复合膜成膜和耐腐蚀机理． 关键词：硅烷；稀土；钝化；交流阻抗 ；耐腐蚀性 中图分类号：TG174．44 文献标识码：A 文章编号：1002-6495(2008)05-0350-03 Ⅱ LUENCE oFSILANE T-APSPRE-FILM oN PASSⅣ ATIoN oFGALVANIZED STEEL BY RARE EARTH LANTIIAN]【】M PENGTian—lan，MANRui-lin，XUBin，QIAOLiang-jie SchoolofChemistryandChemicalEngineering，CentralSouthUniversity，Changsha410083 Abstract：Thesampleofgalvanizedsteelwasfirstlycoatedwithathinserf-assembledmonolayerofsilane (^y—APS)andthenimmersedinarareearthsolutiontogetacomplexcoating．Thecorrosionresistanceof whichwasstudiedbymeansofelectrochemicalimpedancespectroscopyandneutralsaltspray．Theresults showedthatthepre-coatingofsilaneimprovedthecorrosionresistanceofthesamplesignificantly．Atomic forcemicroscopeobservationshowedthatthecomplexcoatingwasmuchuniform anddenser．Analysisre— sultsofX-rayenergydispersivespectroscopyshowedthatthecomplexcoatingwascomposedofN，O，Si， Fe，Zn，La，andtherelativemolefractionofLaofthecomplexcoatingwasneadythreetimeshigherthan thatoftllesinglerareearthcoating．Theresultsalsoshownthatthesilanepre—coatingwasbeneficialtothe depositionofrareearthcoating，thesilanehadasynergisticeffectw