聚羧酸盐高效减水剂的合成与表征.pdfVIP

第 6 期 　　　　　　　　　　　　　　　　　　　　　　化 学 建 材 47 聚羧酸盐高效减水剂的合成与表征 王国建 , 黄韩英 ( 同济大学 材料科学与工程学院, 上海 200092) 摘要 :通过自由基溶液共聚合反应、接枝反应和磺化反应 ,制备了一类主链带羧基、磺酸基 ,支链带聚氧乙烯基醚基 的聚羧酸盐高效减水剂。讨论了主链分子量、侧链长度、磺化度等因素对聚羧酸盐减水剂性能的影响 ,用红外光谱 和凝胶渗透色谱表征了其结构 ,并考察了产品对水泥净浆流动度和混凝土减水率的影响。结果表明 ,本研究制备 的减水剂对水泥粒子有较好的分散作用 ,混凝土减水率可达 30 %以上。 关键词 :聚羧酸盐减水剂 ; 合成 ; 表征 ( ) 中图分类号: TU529 文献标识码 : A 文章编号 :1004 - 1672 2003 06 - 0047 - 05 Synthesis and Characterization of Polycarboxylate High Range Water2reducer / WANG Guo2jian et al / School of Materials Science and Engineering , Tongji University Abstract :Polycarboxylate high range water2reducer with carboxylic groups and sulphonic groups in its main chain and polyoxyethylene ether as side chains was prepared by free radical polymerization , graft reaction and sulphonation. Influences of molecular weigh of main chain , length of side chain and degree of sulphonation on properties of water2reducer were discussed. Structure of water2reducer was characterized by IR and GPC. Influences of the reducer on fluidity of cement paste and water2reducing rate of concrete were investigated. Experimental tests showed that the high range water2 reducer had an excellent dispersing ability for the cement particles and the water2reducing rate of concrete was higher than 30 %. Key words :polycarboxylate water2reducer , 　synthesis , 　characterization 　　随着混凝土向高强、高性能方向发展 ,对外加剂 效减水剂中的长侧链在水泥颗粒表面吸附时形成庞 特别是减水剂提出了更高的要求。自从 1985 年日 大的立体吸附结构 , 同时这一聚合物特有的分子结 本发表了第一篇反应性高分子用于萘系高性能减水 构使其在水泥颗粒表面形成较大的吸附区 ,吸附力 剂的论文之后[1 ] ,减水剂的高性能多功能化成为发 增强。因此高效减水剂不易随水化的进行而脱离颗 展方向。开发减水率高、增强效果好且能有效控制 粒表面 ,即其吸附量随初期水化的进行而