自交联聚氨酯-丙烯酸酯杂化乳液的制备及其膜性能研究-.pdfVIP

: 瀹背濞 绛 鑷氦鑱旇仛姘ㄩ叝 涓欑儻閰搁叝鏉傚寲涔虫恫鐨勫埗澶囧強鍏惰啘鎬ц兘鐮旂┒ - 锛戯紦锛愶紬锛 鏂囩珷缂栧彿: ( ) 锛戯紣锛愶紤-锛欙紬锛擄紤 锛掞紣锛戯紩 锛戯紦-锛戯紦锛愶紬锛?锛愶紨 鑷氦鑱旇仛姘ㄩ叝 涓欑儻閰搁叝鏉傚寲涔虫恫鐨勫埗澶囧強鍏惰啘鎬ц兘鐮旂┒鈭 - , , , 瀹背濞 璧栧皬濞 鐜 钑 鐜 纾 ( , ) 闄曡タ绉戞妧澶у 鏁欒偛閮ㄨ交鍖栧伐鍔╁墏鍖栧涓庢妧鏈噸鐐瑰疄楠屽 瑗垮畨 锛楋紤锛愶紣锛掞紤 : ( )銆 ; ( ), ( ), 鎽 瑕 浠ュ紓浣涘皵閰簩寮傛鞍閰搁叝 鑱氬繁鍐呴叝浜 鍘 鐢插熀涓欑儻閰哥敳閰 涓欑儻閰哥緹涔欓叝 IPDI MMA HEA ( )銆 ( )銆 , ; ( ), 閱 PCL 浜岀緹鐢插熀涓侀吀 DMBA 鍙屼笝閰笝鐑叞鑳 鍖栧绾 澶╂触甯傚寲瀛﹁瘯鍓傚叚鍘 杩囩～閰搁捑 KPS 鍒嗘瀽 ( ) , , ; DAAM 绛変负涓昏鍘熸枡 閲囩敤涔虫恫鑱氬悎娉曞悎鎴愪簡甯告俯 绾 澶╂触甯傜瀵嗘鍖栧璇曞墏鏈夐檺鍏徃 鍙屼笝閰笝鐑叞鑳 銆 ( ), , 鑷氦鑱旇仛姘ㄩ叝 涓欑儻閰搁叝鏉傚寲涔虫恫 閫氳繃鍌呴噷鍙剁孩澶 宸ヤ笟绾 澶╂触甯傝€€鍗庡寲瀛﹁瘯鍓傛湁闄愯矗浠诲叕 - DAAM ( )銆 銆 ( ) ; ( ), , 鍏夎氨 FT-IR 婵€鍏夌矑搴﹀垎鏋愪华 鐑噸鍒嗘瀽 TGA 绛夌爺 鍙 宸变簩閰镐簩閰拌偧 ADH 宸ヤ笟绾 澶╂触甯傚寲瀛﹁瘯鍓傚叚 绌朵簡 鍗曚綋鍚噺銆? )/ ( )姣斿€煎 鍘傘€ DAAM n DAAM n ADH 銆 , ( ) ( ) 涔虫恫鍙婃秱鑶滄€ц兘鐨勫奖鍝 缁撴灉琛ㄦ槑 褰 鑱氭皑閰 涓欑儻閰搁叝鏉傚寲涔虫恫 鐨勫埗澶 m DAAM 锛 锛掞紟锛 - WPUA ,( )/( ) , 銆 锛掞紖 n DAAM n ADH 锛濓紥 鈭讹紤 鏃 鎵€寰楁潅鍖栦钩鑳惰啘 灏 PCL鍔犲叆閰嶆湁鎼呮媽鍣 娓╁害璁″拰姘皵鐨勫洓鍙ｇ儳 銆 銆 , ; , 鐨勮€愭按鎬 鍔涘鎬ц兘鍜岀儹绋冲畾鎬ф渶浼