对氨基苯酚重氮化水解法制备对苯二酚.pdfVIP

广 东 化 工 2010 年 第9 期 · 56 · 第37 卷 总第209 期 对氨基苯酚重氮化水解法制备对苯二酚 沈发治 (扬州工业职业技术学院 化学工程系，江苏 扬州 225127) [摘 要]以对氨基苯酚为原料研究经重氮化、水解法制备对苯二酚的机理、方法，考察了相关工艺条件对制备过程的影响。结果表明，采用 重氮化、水解、萃取分离及后处理的制备过程，在重氮化硫酸浓度15 %～19 %，水解底酸浓度20 % ～40 %且用量适中，水解保温时间4 ～8 h 及选用甲基异丁酮为萃取剂等优化工艺条件下，制备对苯二酚的总收率可达90 % ，且本制备方法具有环境污染少，设备腐蚀小，生产成本低等 优点。 [关键词]对氨基苯酚 重氮化 水解 制备 对苯二酚 [中图分类号]TQ [文献标识码]A [文章编号]1007-1865(2010)09-0056-02 The Preparation of Hydroquinone by Diazotization and Hydrolysis of P-aminophenol Shen Fazhi (Department of Chemical Engineering, Yangzhou Polytechnic Institute, Yangzhou 225127, China) Abstract: The preparation of hydroquinone by diazotization and hydrolysis of p-aminophenol was described, and the mechanism, method, relevant processing conditions in the case was studied. The results showed that using the process of diazotization, hydrolysis, extraction and so on and under the optimal condition of the 15 %～19 % thickness of sulfuric acid in diazotizationis, the 20 %～40 % acid concentration and the 4 ～8 h keeping warm time in hydrolysis, and the methyl butanone as extraction, the 90 % overall yield would be obtained. The method also had advantages of friendly environment, low equipment corrosion, low cost. It was a new method for the preparation of hydroquinone. Keywords: p-aminophenol ；diazotization ；hydrolysis ；preparation ；hydroquinone 对苯二酚即氢醌(HQ) ，又名1,4-二羟基苯，是一种附加值 OH N HSO H O OH OH N H SO 高，用途广泛的化工原料。主要用于摄影