NaY母液回收工艺的探讨.pdfVIP

NaY母液回收工艺探讨 赵 峰 中国石化催化剂齐鲁分公司，山东淄博255336 摘要：中国石化石油化工科学研究院(RIPP)开发的NaY高效合成工艺，水玻璃SiO2的利用率在75％左右。将 NaY晶体与母液分离后，母液单独收集进储罐。NaY母液与硫酸铝溶液通过流量计计量，同时加入到反应釜内， 在搅拌状态下充分混合，控制适当的硅/铝摩尔比和反应pH值，形成硅铝凝胶。经带机过滤，即可制备硅铝胶。 硅铝胶重新用于NaY合成，达到母液回收的目的。 关键词：NaY；母液；SiO2 O643.3 A ASuggestedProcessforUtilizationofMotherLiquorFromNaYSynthesis ZHAOFeng CatalystCompanyQiluDivision,SINOPEC,Zibo255336,China Abstract:TheproblemstobeimprovedincurrentindustrialproductionofNaYarethattheSi (originatedfromrawmaterialsodiummetasilicate)utilizationisonlyaround75％ andtheuntreated alkali-motherliquorsewagecausedseriousenvironmentalpollution. Inthiswork,themother liquor,afterseparatingthesuspendedsolids(NaY)andsomegelatinousmaterials,wasmixed thoroughlywithaluminiumsulfatesolutiontomakesilica-aluminagelforrecyclinguseaspartof theSisourceofthestartingmaterialstosynthesizeNaY.Factorsofusingthesolid-separatedliquor andaluminiumsulfatetopreparesilica-aluminagelincludingthequantityofaluminumsulfate addition,thepHvalue,temperatureandagingtimeofgelation,etc,andtheireffectsonSiloss, filtrationvelocityofSi-Algelareinvestigated. Theexperimentalresultsmakeasuggestionfor raisingprocesseconomyandalleviatingenvironmentalpollution. Keywords:NaY;motherliquor;SiO2 ．，因而 ！滤饼中 『反应温 ：见表2。 5.2 n(Na2O) 固定合成投* n(Na2O)/n(/ SiO2)/n(A12O3 业催化， 2]杨晓虎， 的途径EJ．