光促进下环己烯与二氧化碳羰基化反应中副产物的气相色谱_质谱分析_高大彬.pdfVIP

2005 11 Vol. 23 No. 6 N ovember 2005 Ch inese J ourna l of Chrom atog rap hy 659~ 662 - 高大彬, 尹静梅, 胡皆汉, 周广运, 贾颖萍, 王 锐 (, 116622) : -(GC-M S) CO , 2 CO , 2 CH COCH , CH COCH CD COCD , 3 3 3 3 3 3 GC-M S, M S, CH COCH ) CH cy clo-C H -C (CH ) OH 3 3 3 6 9 3 2 cy clo-C H -C(CH ) OH 3 6 11 3 2 : -; ; ; ; ; ; : O65 8 : A : 1000-87 13(2005)06-0659-04 Analy sis of By-Products in Photoprom oted Carbony lation of Cyclohexene and Carbon D iox ide by Gas Chrom atography-M ass Spectrom etry GAO Dabin, YIN Jingmei, HU Jiehan, HOU Guangyun, JIA Yingping, WANG Rui (L iaon in g P rov in ce K ey La bora tory of B io-O r gan ic Ch em istry, D a lian Un iv er sity, D a lian 116622, Ch in a ) A b stract: The analysis of gas chromatography-m ass spectrometry (GC-MS) has been applied more and more in organic chem istry because of the availability of the mi mediate information from reaction m ixture. In some simple reaction systems, the structures can be determ ined by the comparison of the normalM Sw ith the isotopicMS though usually it is difficult to get struc- tures only from MS. Cyclohexene could also reactw ith acetone to produce by-products in pho- topromoted carbonylati