PTP183.连铸复合式水口内层用镁铝尖晶石质耐火材料的合成研究.pdfVIP

炉用材料 《工业加热》第34 卷2005 年第2 期 连铸复合式水口内层用镁铝尖晶石质耐火材料的合成研究 陈 敏，于景坤，马北越 （东北大学 材料与冶金学院，辽宁 沈阳 110004） 摘要 以镁铝尖晶石为骨料、等摩尔的氧化镁粉和氧化铝微粉为基质料，通过一步固相烧结法合成了水口内层用镁铝尖晶石质耐 : 火材料，考察了原料组成、骨料粒度和成型压力对一步煅烧法制备镁铝尖晶石烧结性能的影响。研究结果表明，随着骨料粒度增 大和基质料含量的增加，试样的烧结性变差，烧成试样的烧后线收缩率变小，显气孔率逐渐增大；随着成型压力的增加，烧成试 样的显气孔率和烧后线收缩都明显减小。以 目尖晶石为骨料，按尖晶石 ∶氧化镁粉 ∶氧化铝微粉＝ ∶ ∶ 配比 （ ）， 80 20 40 40 mol% 并以200 MPa 的压力成型，可以获得结构致密、烧后线收缩率适中的尖晶石质水口内层材料。 关键词：镁铝尖晶石；氧化镁粉；氧化铝微粉；烧结；烧后线收缩率；显气孔率 中图分类号： 文献标识码： 文章编号： ( ) TQ 175.1 A 1002-1639 2005 02-0059-02 Study on Synthesis of Magnesia-alumina Spinel Refractory for Inner-lining of the Submerged Nozzle for Continuous Casting CHEN Min ，YU Jing-kun ，MA Bei-yue （ ， ， ， ） School of Materials and Metallurgy Northeastern University Shenyang 110004 China Abstract : Magnesia-alumina spinel was used as aggregate, magnesia and alumina powder were used as matrix materials, for the synthesis of magnesia-alumina spinel base inner-lining of submerged nozzle (SEN) by solid-state sintering. The effect of composition of starting materials, aggregate size and molding pressure on the sinterability and the properties of samples were studied. The results showed that the sin- terability of samples became poor, the linear shrinkage decreased and the apparent porosity increased with increasing aggregate size and the percentage of matrix materials; The apparent porosity and the linear shrinkage of samples were effectively decreased with incr