固相反应法制备Sn_SnO_Zn纳米负极材料.pdfVIP

37 4 Vol37, No4 2007 8 BATTERY BIMONTHLY Aug, 2007 SnSnOZn 梁 英, 范 晶, 贾志杰 ( 华中师范大学纳米科技中心, 湖北武汉 430079) : 用固相反应法合成了纳米尺寸的SnSnOZn 复合氧化物粉末, 研究了其作为锂离子电池负极材料的电化学性能 XRDSEM 及电化学性能测试的结果显示: 在 800 下焙烧的样品, 首次放电比容量为772 mAh/ g, 首次库仑效率为 601% , 经20 次循环后, 放电比容量为376 mAh/ g; 在600 下焙烧的样品, 首次放电比容量为641 mAh/ g, 首次库仑 效率为494% , 经20 次循环后, 放电比容量只有272 mAh/ g : 锂离子电池; 负极材料; 固相反应; 锡基复合物 : TM9129 : A : 1001- 1 79 ( 2007) 04- 0260- 03 Nano SnSnOZn anode materi al synthesized by solid state reacti on LIANG Ying, FAN Jing, JIA Zhijie ( Centr al of N anoSc ience and Tech nology , H ua Zhong N or mal Univ er sity , W uhan, H ube i 430079, China) Abstract: Nano SnSnOZn composite oxide powder was synthesized by solid state reaction, its electrochemical performance as anode material for Li ion battery was studiedThe results of XRD, SEM and electrochemical performance tests showed that t he initial specific discharge capacity of the sample w hich sintered at 800 was 772 mAh/ g, the initial coulombic efficiency w as 601% , the specific discharge capacity was 376 mAh/ g after 20 cycles; the initial specific discharge capacity of the sample which sintered at 600 w as 641 mAh/ g, t he initial coulombic efficiency was 494% , the specific discharge capacity had only 272 mAh/ g after 20 cycles Key words: Li ion battery; anode material; solid state react ion; tinbased composite , , 20~ 60 nm) Zn 16 g(AR, ) , , , , (AR, ) , 4 h, 80 , , , 600 , , 800 6 h, , , Y2000 X ( ) ,