掺铕氧化钇发光纳米晶的拉曼光谱研究.pdfVIP

20 1 中 国 计 量 学 院 学 报 Vol. 20 No. 1 2009 3 Journal of China University of Metrology Mar. 2009 2009) 0100 004 1 1 1 2 罗宏雷, 刘贵泉 , 邬良能 , 张 伦 ( 1. , 310031; 2. , 22100 ) ~ 50 nm Y O : Eu3+ . XRD 2 3 , Y O : Eu3+ . , 2 3 , Y2 O3 : Eu3+ Raman , Raman , . ; ; ; O433.4 A Raman spectra study on luminescent nanocrystalline Y2 O3 : Eu3+ 1 1 1 2 LU O Honglei , LIU Guiquan , WU Liangneng , ZHANG Lun ( 1. College of Sciences, China Jiliang University, Hangzhou 31001 , China; 2. College of Sciences, China University of Mining and T echnology, Xuzhou 22100 , China) Abstract: Raman propert ies of nanocrystalline ( NCs) Europium doped Yttria ( Y O : Eu3+ ) were 2 3 investigated. The NCs was synthesized by the gel combustion met hod by w hich w e got the NCs from nm to 50 nm. T he t ypical feat ure of Raman shifts at 100 cm- 1 - 500 cm- 1 of this material was measured. We identif ied the Raman shifts of phonon vibration among the spectrum w hich mixed w ith the emission peaks according to the data of bulk Y O : Eu3+ . The spectrum of Raman shifts varied according to the crystalline 2 3 size, and so did t he emission spect rum. A w ide band peak and some new peaks that appeared in the emission spectrum of th