F_TiO_2对锂铝硅微晶玻璃析晶的影响.pdfVIP

31 22 武 汉 理 工 大 学 学 报 Vo l. 3 1 N o. 22 2009 11 JOURNAL OF WUHAN UNIVERSITY OF TECHNOLOGY Nov. 2009 D OI : 10. 3963/ j . issn. 1671443 1. 2009. 22 . 002 F/ TiO 2 郑伟宏, 林墨洲 ( , 430070) : 通过调整F 和T iO2 引入量以降低锂铝硅玻璃的高温粘度和析晶温度, 改善析晶过程, 提高微晶玻璃透明性, 以 应浮法工艺需求并采用X 射线衍射分析研究F 和T iO 2 对锂铝硅系统玻璃析晶影响结果表明: F 的引入可以使 母体玻璃的高温粘度降低, 熔化质量提高, 初始析晶峰温度降低F 引入之后随着T iO2 含量的减少, 初始析晶峰温度升 高, 析出主晶相的种类没有发生改变, 都为石英固溶体当F 和T iO2 的引入量分别为0 . 8% 和1. 0 % 时, 随着晶化温 度的升高, 析出的主晶相为石英固溶体, 透明性变差, 并且随着晶化时间的延长, 析出的石英固溶体含量逐渐增加, 透明性变差 : 锂铝硅微晶玻璃 析晶 F T iO2 : T Q 171. 7 33 : A : 167144 31( 2009) Effect of F and TiO on the Cr stallization of Lithium 2 Aluminosilicate Glassceramics ZH EN G Weihong , L IN M oz hou ( Key L aboratory of Silicate M aterials Science and Engineering of M inistr y of Educat ion, Wuh an U niversity of T echnolog y, W uh an 430070 , China) Abstract: T he addition s of F and T iO 2 w ere changed f or decreasing v iscosity and crystallization temperature and improving the tran sparency of the lithium alum inosilicate g lassceram ics f or float process . T he effect of diff erent addit ions on the crystal lizatio n of specim ens w as investigated by m eans of XRD. T he result s sho w that the addition of F decreases the viscosity and crystallization temp er ature o f g lasses. T he crystallization temp erature is incr eased and the m ain phase is quartz w ith the add