分散聚合制备聚苯乙烯微球及影响因素研究.pdfVIP

Material Sciences 材料科学, 2013, 3, 40-44 doi:10.12677/ms.2013.31008 Published Online January 2013 (/journal/ms.html) Preparation and Effects of Polystyrene Microspheres by * Dispersion Polymerization # Long Zhou, Jinhui Dai , Fei Zhan Ocean University of China, Qingdao Email: #daijh1@ Received: Dec. 13th th th , 2012; revised: Dec. 29 , 2012; accepted: Jan. 4 , 2013 Abstract: Polystyrene microspheres sized in sub micron were prepared by a dispersion polymerization with PVP as dispersant, H O and ethanol as reaction medium, AIBN as initiator. The effects of H O-ethanol ratio, string speed and 2 2 amount of styrene, AIBN and PVP on particle size and distribution were discussed. Results show that PS spheres size could be preliminarily control. The component of reactant is the main effect of size and distribution, meanwhile, spin rate only effects sphere size. Keywords: Dispersion Polymerization; Polystyrene Microsphere; Particle Size Distribution 分散聚合制备聚苯乙烯微球及影响因素研究* # 周 珑，戴金辉 ，展 飞 中国海洋大学，青岛 Email: #daijh1@ 收稿日期：2012 年 12 月 13 日；修回日期：2012 年 12 月 29 日；录用日期：2013 年 1 月 4 日 摘 要：以聚乙烯吡咯烷酮为分散剂，水及无水乙醇为反应介质，偶氮二异丁腈引发剂，采用分散聚合的方法， 制备出了一系列亚微米级的 PS 微球，分析了单体、引发剂、分散剂的用量，反应介质组成和搅拌速度对产物粒 径及粒径分布的影响。结果表明，利用分散聚合，初步实现了 PS 粒径的可控，反应物组成对微球粒径及分布起 主要作用，而搅拌速率只对微球粒径有影响，对粒径分布影响不大。 关键词：分散聚合；聚苯乙烯微球；粒径分布 1. 引言