二亚乙基三胺五乙酸修饰的固体汞合金电极测定铬_和无机态铬_乐上旺.pdfVIP

·378 · 　2008 5 　　　　　　　　　　 ttp: (Ⅵ )(Ⅲ) 1 1, 2 ＊ 1 乐上旺 　李建平 　林庆宇 1 2 (　　541004;　　　541004) 　　Cr(Ⅲ)-(DTPA)-NO3 - (Ⅵ )(Ⅲ)。 , DTPA。 0.1mol L HAc-NaAc (pH=5.5)0.25mol L KNO , -0.80～-1.40V , 3 Cr6+ Cr3+ DTPA , (Ⅲ) DTPA , -1.24V 。, (Ⅵ )(Ⅲ) -9 -6 -8 -6 。 (Ⅵ )(Ⅲ):5.0×10 ～ 5.0×10 mol L 1.0×10 ～ 5.0×10 mol L, -10 -9 1.6×10 mol L 5.1×10 mol L。 11 4.3%。 , Cr(VI)Cr(Ⅲ)98.5%～ 105.0%。 　　　　DTPA Determination of Cr(VI)and Inorganic Cr(Ⅲ) using Solid Amalgam Electrode Modified with DTPA 1 1, 2 ＊ 1 Le S angwang , Li Jianping , Lin Qingyu 1 (Department of Material and C emical Engineering, Guilin University of Tec nology, Guilin 541004; 2 T e Guangxi Key Laboratory of Enviromental Engineering Protection and Assessment, Guilin 541004) Abstract　Solid silver-amalgam electrode modified wit diet ylenetriaminepentaacetic acid (DTPA ) as been fabricated to detect c romium species utilizing t e electrode surface DTPA pre-extraction and t e catalytic system Cr(Ⅲ)- DTPA-NO - .Cr(VI)in solution as been reduced to Cr(Ⅲ)and pre-concentrated on t e surface of t e electrode to form 3 complex, and t en, Cr(Ⅲ)-DTPA complex is reduced and a sensitive reduction peak was produced at -1.2