纤维板防水剂用石蜡_松香乳液的组成及其性能研究.pdf

25 2 Vo.l 25 No. 2 2005 6 Chem istry and Industry of Forest Products June 2005 - * 吴宗华, 陈少平, 孙秀武, 李爱民 (福建师范大学 化学与材料学院, 福建 福州 350007) : 采用专用高分子表 活性剂和转相法制备了系列石蜡-松香乳液, 并考察了这些乳 液中的表 活性剂种类和石蜡与松香的质量比对中密度纤维板防水性和力学性能的影响研 究结果表明,用苯乙烯和丙烯酸及其衍生物为单体的高分子表 活性剂(H S)和烷基苯聚氧化 WU H 乙烯醚衍生物的低分子表 活性剂( LS)的混合物能制得稳定的石蜡-松香乳液表 活性剂 3 用量为 5 kg /m 时石蜡-松香(质量比 12)乳液使纤维板的吸水厚度膨胀率减少 23. 8% , 而弹性模量增加了 12. 2 % 表 活性剂的组成和石蜡与松香的质量比都显著地影响乳液的性能和使用效果 : 石蜡-松香乳液; 高分子表 活性剂; 纤维板; 防水剂 : TQ351. 471; TS653. 6 : A : 0253- 2417(2005) 02- 0095- 04 RELATIONSH IPS BETWEEN COMPOSIT ION AND PERFORMANCE OF WAX-ROSIN EMULSION ASWATER-REPELLENT OF FIBREBOARD WU ong-hua, CHEN Shao-ping, SUN X iu-wu, LIA -im in ( Co lleg e of Chem istry and M ater ia ls, F uj ian N orm al Un iv er sity, F uzhou 350007, Ch ina) Abstrac t: Series ofw ax-rosin em ulsionw ere prepared using polymeric surfactants designed for the em ulsion, and the effects of structure of the surfactant and the m ass ratio of w ax and rosin on the properties of the em ulsion w ere investigated. The resu lts show ed that stable w ax-rosin em ulsion could be prepared using m ixture of polymeric surfactant and the low molecu lar surfactants( LS) of derivative of alkylbenzyl polyoxyethyene ether. The polymeric surfactant (H S) w asm ade from styrene, acrylic acid and its derivative. The use of em ulsion at the mass ratio 12 of w ax and rosin cou ld reduce the adsorbing-w ater expansion coefficient of fibreboard by 23. 8 % and increase the