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多种金属/TiO2核壳纳米棒阵列的通用制备方法.pdf
CHINESE J0URNAL 0F CHEM ICALPHYSICS VOLUM E 24,NUMBER 1 FEBRUARY 27,2011
ARTICLE
SynthesisofVariousMetal/TiO2Core/shellNanorodArrays
WeiZhu,Guan—zhongW ang ,XunHong,Xiao—shuangShen
HefeiNationalLaboratory forPhysicalSciencesatMicroscale,DepartmentofPhysics,University of
ScienceandTechnologyofChina,Hefei230026,China
(Dated:ReceivedonOctober11,2010;AcceptedonNovember15,2010)
W_epresentageneralapproachtofabrk:atemetal/TiO2core/shellnanorodstructuresbytwo—
stepelectrodeposition.Firstly,TiO2nanotubeswithuniofrm wallthicknessarepreparedin
anodicaluminum oxide(AA0)membranesbye1ectrodeposition.Thewallthicknessofthe
nanotubescould beeasilycontrolled bymodulatingthedepositiontime,and theirouter
diameterandlengthareonlylimitedbythechanneldiameterandthethicknessoftheAA0
membranes,respectively.Thenanotubes’topsprepared by thismethod areopen,while
thebottomsareconnecteddirectlywith theAufilm atthebackoftheAA0 membranes.
Secondly,Pd,Cu,andFeelementsarefilledintotheTiO2nanotubestoform core/shell
structures.Thecore/shellnanorodspreparedbythistwo—stepprocessarehighdensityand
free—standing.andtheirlengthisdependentonthedepositiontime.
Keywords:Titania,Nanotube,Core/shell,Electrodeposition,Membrane
I.INTR0DUCT10N anodizedTiO9nanotubescouldbeopdnedbysoaking
thewetTi02nanotubemembranesinNH4FandH2S04
TitaniafTi02)isaninexpensive,non—toxic chemi— solution,onfortunatelythesurfaceofthetubeswould
calstablematerialwithexcellentphysical,andchem— alsobepartlyerodedatthesametimef181.Inaddition,
itisdimculttoopen allthebottom endsatthesame
icalperformance. It hasbeen investigated for ap—
plicationsin photocatalysis,photocleavage ofwa
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