煤气化污水酚回收中脱酸塔的技术改造.pdfVIP

化 学 工 程 师 Sum 178 No.7 Chemical Engineer 2010 年第7 期 文章编号：1002-1124 （2010）07-0060-03 生 产 与 技 术 煤气化污水酚回收中脱酸塔 改 造 的技术改造 周永涛，李旭光 (中煤龙化哈尔滨煤化工有限公司，黑龙江哈尔滨154854) 摘 要：煤气化污水酚回收化工流程处理中，脱酸塔主要是脱除其中的酸性气体。长期运行中脱酸塔存 在处理量小、易结垢、效率低、运行不稳定等问题。本文通过改变塔内件、增加塔板数量以及采用惰性气体消 泡、解析技术，很好地解决出现的问题，避免塔液泛增加处理能力。结果显示，采用斜孔塔板及惰性气体消泡 等技术后，运行稳定，达到预期目标。 关键词：脱酸；塔板；消泡；液泛 中图分类号：TQ028.1 文献标识码：B Technological upgrading of deacidification tower in the phenol recovery of coal gasification wastewater ZHOU Yong- tao ，LI Xu-guang （Dragon of Harbin Coal ，Coal Chemical Co. ，Ltd. ，Harbin 154854 ，China） Abstract: In the chemical process of ammonia and phenolic recovery in coal gasification wastewater, deacidification tower was mainly used to remove acid gas. After long-term operation, it was found that the capacity of deacidification tower was small, the efficiency was low, and the deacidification tower was easy to scale, operation instability. These problems were resolved through changing the tower parts, increasing the tray number and the use of inert gas foaming, analytical techniques, and avoid the tower flooding to increase the handling capacity. The results showed that, after the use of slant-hole tray and the anti-foaming technology by inert gas, the operation was stability, and achieve the desired objectives. Key words: deacidification ；tray ；anti-foaming ；flooding 中煤龙化哈尔滨煤化工有限公司主工艺是采 醚，冷凝后回用；从侧线采出氨水汽。釜液处理后的 用PKM 加压气化炉对硬质褐煤进行加压气化生产 废水进入后续的生化处理工序。 城市煤气和工业甲醇。针对煤气化污水处理的酚回