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59 4 Vol59 No4
2008 4 Journal of Chemical Industry and Engineering ( China) pril 2008
SnSO4
靳会杰, 李燕红, 任保增, 孔海平, 雒廷亮, 刘国际
( , 450001)
: SnSO ; ; ;
4
: O 64213 : A : 0438- 1157 (2008) 04- 0917- 03
Thermal decomposition of SnSO4 in catalyst preparation
JIN Huijie, LI Yanhon , REN Baozen , KONG Haipin , LUO Tin lian , LIU Guoji
(S chool of Chemical Eng ineering , Zhengz hou Univ ers ity , Zhengz hou 450001, H enan, China)
Abstract: SnSO4 is an important promoter of catalyst for preparing naphthalene quinone with oxidation of
naphthalene by airIts thermal decomposition kinetics in N2 was studied with NETZSCHST 409PC
thermal analyzerSnSO4 thermal decomposition was an endothermic reaction and mainly occurred at 450-
550 The total mass loss was 2936%, so the reaction products were SnO2 and SO2Kineticfunction was
obtained and kinetic parameters were calculated with linear regression provided by NETZSCH Instruments
CoLtdT he correlation coefficient was 09997The results showed that SnSO4 decomposition was a self
catalysis reaction and the catalyst was its reaction productT he kinetic function predicted that SnSO4
decomposition was 20% at 450 for 120 min and 100% at 480 for 106 min, and the process of catalyst
preparation can be optimized.
Key words: SnSO4 ; thermal decomposition; kinetics; thermal analysis
, ,
(T G) ,
[ 1]
, ,
[6]
, SnSO4
, , , SnSO4
[2] SnSO4 ,
TG
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