人工碳纳米材料悬浊液的制备及其浓度测定方法.pdfVIP

第4卷 第5期 324 中国科技论文在线 Sciencepaper Online 2009 年 5 月 人工碳纳米材料悬浊液的制备及其浓度测定方法 刘信勇，朱 琳 （南开大学环境科学与工程学院；环境污染过程与基准教育部重点实验室，天津 300071） 摘 要：采用加入表面活性剂SDS ，并超声波振荡的方法制备了2 种纳米材料（碳纳米管和富勒烯）的悬浊液，使其 在水溶液中均匀分散。浓度测定前滤去悬浊液中的大颗粒，以达到进样要求。分别用TOC分析仪和称重法测定不同悬 浊液的含碳浓度，结果显示两者无显著性差异，这证明TOC测定方法有效，且简单可行。将测定样品稀释不同倍数， 利用TOC分析仪测定不同静置时间的悬浊液含碳浓度，结果显示该方法制备的悬浊液分散均匀，静置 14 d后浓度变化 不大。超声振荡时间越长，加入的碳纳米材料和表面活性剂越多，分散于水体中的碳纳米材料就越多。 关键词：环境污染及其防治；多壁碳纳米管；富勒烯；总有机碳；悬浊液；浓度测定，纳米材料 中图分类号：X502 文献标识码：A 文章编号：1673－7180(2009)05 －0324 －5 Preparation of the carbon nanomaterials suspension and the determination of their concentrations by TOC Liu Xinyong ，Zhu Lin (College of Environmental Science and Engineering; Key Laboratory of Pollution Processes and Environmental Criteria (Nankai University), Ministry of Education, Nankai University, Tianjin 300071, China) Abstract: The suspension of two kinds of carbon nanomaterials (carbon nanotubes and fullerenes) were prepared by surfactants (SDS) addition and ultrasonic vibration. Carbon content of different suspension measured after filtration, by TOC analyzer and weighing method,.did not show significant difference of the results, which proved the validity and practicability of the TOC method. Measurment of carbon content in suspension with a series of dilution ratio and different stewing time,indicated that the suspension prepared in this way could be dispersed evenly, and there was little change in concentration in 14 days. In addition ，dispersing carbon nanomaterial increased with the increase of vibration time, and the amount of surfactant and carbon nanomaterial. Key words: environmental pollution and control ；multi-wall carbon nanotubes ；fullerenes ；TOC ；suspension; concentration determination ；nanomateri