CuTi-MCM-41,CuTi-HMS 的制备表征与脱硫性能.pdfVIP

第29 卷第3 期 高 校化 学 工程 学 报 No.3 Vol.29 2015 年 6 月 Journal of Chemical Engineering of Chinese Universities June 2015 文章编号：1003-9015(2015)03-0578-07 Cu/Ti-MCM-41,Cu/Ti-HMS 的制备表征与脱硫性能 王广建, 张金龙, 杨志坚, 褚衍佩 (青岛科技大学 化工学院, 山东 青岛 266042) 摘 要：以水热合成法成功合成了Cu/Ti-MCM-41 、Cu/Ti-HMS介孔分子筛，采用XRD 、SEM、TEM 、FT-IR 、BET等 手段对分子筛进行了表征。结果表明，合成的分子筛具有良好的晶体结构，Ti 已进入分子筛骨架，Cu元素以氧化物CuO 形式存在于分子筛表面并使得分子筛孔道直径分布更集中。用H 2 O2 为氧化剂，合成的Cu/Ti-MCM-41 、Cu/Ti-HMS分 子筛为催化剂，用于氧化脱硫反应，实验结果表明，CuO 的π键复合配位吸附作用可有效提高Cu/Ti-MCM-41 、Cu/Ti-HMS 的脱硫性能，脱硫率达到92.8% 、88.5% ；再生后，分子筛的脱硫率有所下降，表面CuO 的流失和分子筛结构的坍塌是 导致Cu/Ti-MCM-41 、Cu/Ti-HMS脱硫性能下降的原因。 关键词： Cu/Ti-MCM-41 ；Cu/Ti-HMS ；合成；表征；脱硫 中图分类号：TQ424.25 ；TE624.1 文献标识码：A DOI ：10.3969/j.issn.1003-9015.2015.03.012 Preparation, Characterization and Desulfurization Performance of Cu/Ti-MCM-41 and Cu/Ti-HMS Catalysts WANG Guang-jian, ZHANG Jin -long, YANG Zhi-jian, CHU Yan -pei (Department of Chemical Engineering, Qingdao University of Science and Technology, Qingdao 266042, China) Abstract: Cu/Ti-MCM-41, Cu/Ti-HMS mesoporous molecular sieves have been successfully synthesizd by hydrothermal synthesis. The samples were characterized by XRD, SEM, TEM, FT-IR, and BET techniques. The results show that the molecular sieve has the favourable crystal structure and Ti is located in framework of the molecular sieve, Cu element in the form of oxide CuO exists in molecular sieves, which makes the distribution of molecular sieve surface channel diameter more concentrated. Cu/Ti-MCM-41 and Cu/Ti-HMS were used as heterogeneous catalyst for the oxidative desulfurization reaction wit