PS-b-PNIPAMAg复合微粒的制备与表征.pdfVIP

理化学学报(Wuli Huaxue Xuebao) November A cta Phys. Chim. Sin., 2009, 25(11) ：2399-2403 2399 [Article] PS b PNIPAM/Ag 复合微粒的制备与表征 博 雷忠利 杨 红 李 娜 (应用表面与胶体化学教育部重点实验室, 陕西师范大学化学与材料科学学院, 西安 710062) 摘要： 采用原子转移自由基聚合(ATRP)法合成了聚苯乙烯b 聚(N 异丙基丙烯酰胺)(PS b PNIPAM)两亲性嵌 段共聚 , 并以其为模板, 聚乙烯亚胺(PEI)作为银离子和嵌段共聚 PS b PNIPAM 的交联剂以及还原剂, 制备 了PS b PNIPAM/Ag 复合纳米微粒. 利用透射电子显微镜(TEM) 、X 射线衍射(XRD)和傅里叶变换红 (FTIR)光 谱对复合纳米微粒的形貌及其成分进行了表征. X 射线衍射和电子衍射证明银纳米微粒具有良好的面心立方体 单晶结构. 研究结果表明, 不同浓度的两亲性嵌段共聚 PS b PNIPAM 在丙酮中形成的胶束模板对银纳米粒子 的尺寸及其分布有重要的影响. 关键词： 纳米银微粒; 两亲性嵌段共聚 ; 原子转移自由基聚合; 聚乙烯亚胺 中图分类号： O648 Preparation and Characterization of PS b PNIPAM/Ag Composite Particles MU Bo LEI Zhong Li YANG Hong LI Na (Key Laboratory of App lied Surf ace and Colloid Chemistry, Ministry of Education, School of Chemistry and Materials Science, Shaanxi Normal University, Xi 忆an 710062, P. R. China) Abstract ： Amphiphilic diblock polystyrene b poly(N isopropylacrylamide) (PS b PNIPAM) was used as a template for metal block copolymer nanocomposite formation. Diblock copolymers were synthesized using the atom transfer radical polymerization (ATRP) method . Polyethyleneimine (PEI) acted as a crosslinking agent between Ag ions (Ag nanoparticles) and PS b PNIPAM colloids and was the reducing agent during the formation of Ag nanoparticles. The product was characterized by Fourier transform infrared (FTIR) spectroscopy, X ray diffraction (XRD), and transmission electron microscop