EESc0ee00717j_O2在SOFC固体电解质中的扩散机理.pdfVIP

View Online / Journal Homepage / Table of Contents for this issue Dynamic Article Links Energy C Environmental Science Cite this: Energy Environ. Sci., 2011, 4, 2774 /ees PERSPECTIVE Oxygen diffusion in solid oxide fuel cell cathode and electrolyte materials: mechanistic insights from atomistic simulations *ab *c *d a *a Alexander Chroneos, Bilge Yildiz, Albert Tarancon, David Parfitt and John A. Kilner Received 26th November 2010, Accepted 21st April 2011 2 DOI: 10.1039/c0ee00717j 1 J 0 7 2 1 t 7 s 0 u 0 Solid oxide fuel cells are of technological interest as they offer high efficiency for energy conversion in g E u A E a clean way. Understanding fundamental aspects of oxygen self-diffusion in solid state ionic systems is 0 6 C 0 / n 9 important for the discovery of next-generation electrolyte and cathode material compositions and 3 o 0 y 1. microstructures that can enable the operation of SOFCs at lower temperatures more efficiently, g 0 o 1 l : durably, and economically. In the present perspective article, we illustrate the important role of o i n o h d modelling and simulations in providing direct atomic scale insights on the oxygen ion transport c | e g T r mechanism