《A Threedimensional BaⅡ Coordination Polymer Based on H4AQTC Anthraquinone1458tetracarboxylic AcidQuinone Oxygen Atoms Participate in Coordination》.pdfVIP
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34卷I期 结构化学 0jlEjGoUHUAxUE、 Vbl.34.No.1
2015.1 Chinese√: Struct.Chem. 133一139
AThree-·dimensionalCoordinationBasedon
Ba(11) Polymer
Acid):
QuinoneAtoms in
OxygenParticipate
YAN Li.Bin
Wei.Hong②YANG
SHEN JIE--Yu
Ming·-Le
and
(NanyangKeyLaboratoryofIndustrialMicrobiology,SchoolofBiology
Institute 473004,China)
ChemistryEngineering,NanyangofTechnology,Nanyang
ABSTRACTAnovelcoordination 2
polymer[Ba2(AQTC)(H20)3]。(1,H4AQTCanthraquinone一
been under conditionsandcharacterized
acid)has by
1,4,5,8一tetracarboxylic preparedhydrothermal
and
X—raydiffraction,elementalanalysis,infraredspectroscopythermogravimetric
single-crystal
atomsandall atomsof involvedin
quinoneoxygen carboxylateoxygen AQTC4一are
analysis.Two
coordination.Twobariumionsare linked atomsintoa
equivalent mainly bycarboxylateoxygen
arefurtherconnectedthe
dimers AQTC+ligandthroughcarboxylate
dimer.Neighbouring by
are further
toaI-Dchain two chainsmainly
atom,lea
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