以β-Si3N4为晶种多孔氮化硅陶瓷的制备.pdfVIP

第37卷第5期 人 工 晶 体 学 报 V01．37No．5 2008年IO月 JOURNALOFSYNTHE7FICCRYSTALS October．20()8 N4为晶种多孔氮化硅陶瓷的制备 以13I—Si3 贾玲，谷景华，张跃 (北京航空航天大学材料科学与工程学院学院，北京100083) 陶瓷，研究了B·Si，N。晶种添加鼍对其物相、微观形貌和弯曲强度的影响。结果表明，加入B．Si，N。晶种能有效地促 进q-Si，N。转化为B·Si，N。，经1580oC烧结的氮化硅陶瓷中出现了明显的长柱状晶粒，随着晶种添加量的增加，柱 状晶的长径比逐渐增大，且柱状晶的产生可提高材料的强度。 关键词：氮化硅；多孔陶瓷；强度 中图分类号：TQl74 文献标识码：A ofPorousCeramicswith asSeeds PreparationSi3N4 pSi3N4 Yue JIA崩W，GUJing—hua，ZHANG ofMaterialsScienceand of and Aeronautics (School Engineering，BeijingUniversity Astronautics，Beijing100083，China) (Received23如n“dy2008) ceramicswith were Abstract：Porous Si3N4 30％porositypreparedfrom仅一Si3N4powderbyusingB·Si3N4 asseedsand as additives．Theeffectof seedsonthe MgO—A12 0s-Si02sintering B—Si3N4 phase， microstructureand of ceramicswasstudied．Itwasshowed bendingstrengthporousSi3N4 phase transformationwasfavoredtheadditionof rod—like whichcould by B—Si3N4seeds，and crystalparticales enhance the of ceramicscouldbeobserved inmaterialssintered bendingstrengthporousSi3N4 apparently at1580oC．Theslendernessratioincreaseswith ofthe of seeds． the content rising B．Si3N4 words：silicon Key nitfide；porousceramics；bendingstre