促进型PtMoSiC催化剂的制备、表征及电催化活性.pdfVIP

理化学学报 Wuli Huaxue Xuebao 92 Acta Phys. Chim. Sin., 2007, 23 1 ：92-97 January [Article] 促进型PtMoSi/C 催化剂的制备、表征及电催化活性 育芬 刘军民 廖世军 华南理工大学化学科学学院, 广州 510641 、 摘要： 采用甲醛还原 H 还原、肼还原三种方法制备了添加硅钼酸的PtMoSi/C 阳极催化剂, 并用XRD 、XPS 和 2 TEM 技术对催化剂进行了表征. XRD 表明Pt 粒子呈立方面心晶态结构, TEM 显示PtMoSi/C 催化剂粒径小 3- 4 nm , 分布窄, 分散性好. XPS 分析可知Pt 主要以0 价, Mo 主要以6 价, Si 主要以4 价形态存在于催化剂中. 同 时通过循环伏安法和线性扫描法考察了制备方法和添加硅钼酸对催化剂电化学活性的影响. 结果表明, 甲醛还 原法制备的PtMoSi/C 催化剂 Pt、Mo 的原子比为3 1 对甲醇氧化的电化学性能和抗中毒性能优于自制的PtRu/ C 和E鄄TEK PtRu/C 催化剂, 可能是因为添加硅钼酸可以使活性组分的分散度提高, 从而提高了催化剂的活性和 抗毒性能. ； ； 关键词： 硅钼酸 直接醇类燃料电池 催化剂 中图分类号： O643.36 Preparation, Characterization and Electrocatalytic Properties of Promoted PtMoSi/C Catalysts CAI Yu鄄Fen LIU Jun鄄Min LIAO Shi鄄Jun College of Chemistry, South China University of Technology, Guangzhou 510641, P. R. China Abstract ： PtMoSi/C nanocatalysts were prepared by chemical reduction using formaldehyde, H , and hydrazine as 2 reducing agents , respectively . The nanocompositions were characterized by X 鄄ray diffraction XRD , X鄄ray photoelectron spectroscopy XPS , and transmission electron microscopy TEM . XRD patterns showed a face鄄centered cubic crystal structure, and TEM images indicated that the nanoparticles that were uniformly dispersed on carbon were 3-4 nm in diameter. XPS analysis revealed that the catalysts contained mostly Pt 0 , Mo VI , and Si IV . The effects of preparation methods and additives on the catalytic activity were then studied by linear sweep voltammetry LSV and cyclic voltammetry CV . It was found that the PtMoSi/C nanocatalysts nPt nMo 3 1 was the optimal ratio of Pt to Mo prepared using formaldehyde as reducing agent showed higher electrocatalytic activity and better tolerance to poisoning species in methanol oxidation compared with the homemade PtRu/C and the commercial E鄄TEK PtRu/C catalysts, and this could be ascribed to the high dispersion of Pt nanoparticles on the carbon by the addition of silicomolybdic acid. Key