分散聚合制备聚苯乙烯微球.pdfVIP

分散聚合制备聚苯乙烯微球 胡 杰，袁新华，曹顺生 (江苏大学材料科学与工程学院，江苏镇江212013) 摘要：以苯乙烯为单体，聚乙烯基吡咯烷酮(PVP)为分散稳定剂，偶氮二异丁腈(AIBN)为引发剂， 研究了分散聚合体系中各组分，如单体、分散介质和引发剂等用量的变化对聚合物微球的粒径大小 及粒度分布的影响，并利用扫描电子显微镜对微球表面形貌进行了观测．结果表明，体系中的单体 浓度、分散介质特性、引发剂用量对所制备微球的粒径大小及粒度分布具有重要影响．通过调整配 方，选择合适的工艺参数，可成功制备出粒径2—5p．m、单分散，陆良好的聚苯乙烯微球，且微球表面 光洁，外形均匀对称。相互之间没有粘连． 关键词：聚苯乙烯；聚合；微球；粒径；粒径分布 中图分类号：0631 文献标志码：A 文章编号：1671—7775(2009)04—0370—04 of Preparationpolystyrenemicrospheres bydispersionpolymerization Hu．，如。YuanXinhua，Cao Shunsheng ofMaterialScienceand (School Engineering，JiangsuUniversity。Zhenjiang，Jiangsu212013，China) as as AIBNas effects monomer，PVPdispersionstabilizer，andinitiator，the Abstract：Byusingstyrene size of in onthe andsizedistributionwerestudied． polymerization particle componentsdispersion systems Thesurface ofthe wasobservedSEM．Itisfoundthatthe ofthe pattern polymermicrosphere by change monomer characteristicsandtheamountoftheinitiatorwill affectthe content，medium markedly particle sizeandsizedistributionofthe reaction preparedpolymermicrospheres．Throughelectingproper parame— sizeof2～5 were withclean inthe pLm synthesized surface，uniform ters。monodispersedmicrospheres no externality，andcoagulation． sizedistribution Keywords：polystyrenes；polymerization；microsphere