非常重要的制备TiO2的文献.pdf

Available online at Thin Solid Films 516 (2008) 4613 – 4619 /locate/tsf Fabrication of thin film dye sensitized solar cells with solar to electric power conversion efficiency over 10% Seigo Ito ⁎, Takurou N. Murakami 1, Pascal Comte 1, Paul Liska 1, Carole Grätzel 1, Mohammad K. Nazeeruddin 1, Michael Grätzel ⁎ Laboratoire de Photonique et Interfaces, Institut des Sciences et Ingénierie Chimiques, École Polytechnique Fédérale de Lausanne (EPFL), Station 6, CH-1015, Lausanne, Switzerland Available online 14 June 2007 Abstract Techniques of TiO 2 2 film fabrication for dye-sensitized solar cells having a conversion efficiency of global air mass 1.5 (AM 1.5, 1000 W/m ) solar light to electric power over 10% are reported. Newly implemented fabrication technologies consist of pre-treatment of the working photoelectrode by TiCl4, variations in layer thickness of the transparent nanocrystalline-TiO2 and applying a topcoat light-scattering layer as well as the adhesion of an anti-reflecting film to the electrodes surface. TiCl4 treatments induce improvements in the adhesion and mechanical strength of the nanocrystalline TiO2 layer. Optimization of the thickness of the TiO2 layer, acting as the working electrode, affects both the photocurrent and the photovoltage of the devices. Covering of the TiO2