射线辐照对蓖麻油基聚氨酯灌封胶性能的影响.pdfVIP

33 2 四川大 学 学 报( 工程 科 学版) Vol. 33 No. 2 2001 3 JOURNAL OF SICHUAN UNIVERSITY ( ENGINEERING SCIENCE EDITION) Mar. 2001 : 100 3087( 2001) - 关 键, 罗祥林, 乐以伦 ( , 610065 ) : 5 - , ( HPLC) 4, 4- ( MDA) , - , - , MDA 25 kGy - , 5 MDA 103310371052105 10 1g/ g, MDA - , ( ) , : ; ;- ; : TQ 432. 2 :A Effects of - ray Irradiation onProperties of Castor Oilpolyurethane Potting Materials G UAN Jian, L UO X ianglin, YUE Yilun (Dept. of Polymer Materials Eng. , Sichuan Univ. , Chengdu 610065, China) Abstract:After - ray sterilization, the amounts of 4, 4- methylenedianiline (MDA) in the five kinds of synthesized medical castor oilpolyurethane potting materialswere detected by HPLC. The influences of - ray irradiation on the me chanical performance of the potting materials were also discussed quantitatively. The experimental results showes that the amounts of produced MDA increaseswith - ray irradiation dosagee. After 25 kGy - ray sterilization, the accumulated amounts of MDA in the five kinds of potting materials were 10. 33, 10. 37, 10. 52, 10. 5 , 10. 1g/ g respectively. Those amounts are below the level of harmamount to human body. At the same time, the mechanical properties of the potting materials such as tensile strength, tear strength and hardness are improved because crosslinking happens under irradiation. Key words:polyurethane; potting materials; - ray; irradiation , 1 88 245 kt 15 kt, 1 3 28 kt 1 kt 1 85 - , 204 kt, 1 0 28kt , , (MDI) [ 1] , ,