武大物理化学练习题.docVIP

一、（45分）填空及单项选择 1．??181 cm的惰性多孔板两边，放置扩散系数为1.19×10-9?m2???s-1的NaCl稀水溶液，一边浓度为0.4 mol?dm-3，另一边为0.2 mol?dm-3。两边溶液量很大，且一直在搅拌。则溶质NaCl的物质通量为????????????????????????????NaCl的浓度在板内的分布为??????????????????? 2．??A─→2B在温度?T?时的速率方程为?d[B]/dt=kB[A]，则此反应的半衰期为：(?? ???) (A)? ln 2/kB??????? (B)? 2ln 2/kB?? ????(C)??kBln2?? ???????(D)? 2kBln2?? 3．True or false (a)????Elementary reactions with molecularity greater than 3 generally dont occur;??????????? (b)????Knowledge of the rate law of a reaction allows us decide unambiguously what the mechanism is;????????????????? (c)????Activation energies are never negative;??