载银TiO2纳米管阵列的光催化和抗菌性能研究.docVIP

载银TiO2纳米管阵列的光催化及抗菌性能研究 王海蓉，霍开富* 武汉科技大学材料与冶金学院，430081，武汉 E-mail： 采用阳极氧化法在Ti基底上制备TiO2纳米管阵列，然后将其放入AgNO3溶液中，通过紫外光化学还原方法，得到载Ag纳米粒子的TiO2纳米管阵列（Ag-TNA）。结果表明负载银纳米粒子后的TiO2纳米管的光催化性能明显提高，同时具有很好的抗菌性能。进一步研究表明，在1M AgNO3溶液中，光化学还原循环处理两次得到的载银TiO2纳米管阵列（1M-2次 Ag-TNA）] B. O’Regan and M. Graetzel, Nature, 1991, 353, 737 [2] F. Zhang, J. Zhao, T. Shen, H. Hidaka, E. Pelizzetti and N. Serpone,Appl. Catal. B. Environ. 1998, 15, 147 Photocatalytic and Antibacterial Properties of TiO2 Nanotube Arrays Loaded with Ag Nanoparticles Hai-Rong Wang, Kai-Fu Huo* School of Materials and Metallurgy, Wuhan University of Science and Technology, 430081, Wuhan Titania nanotube arrays decorated silver nanoparticles (Ag-TNAs) were prepared on Ti foil via electrochemical anodization of Ti in a fluoride-containing solution and subsequent photochemical reduction of absorbed AgNO3 solution under ultraviolet irradtion. The results show that the photocatalytic activity of Ag-TNAs is much better than that of TiO2 nanotubes. Further investigations suggest that the Ag-TNAs prepared by soaking in 1 M AgNO3 and subsequently photoreducing for two runs (1M-2 Ag-TNA) have the best photocatalytic degradation activity and anti-bacterial properties. (b) (a) Fig. 2 antibacterial property of anatase TiO2 and Ag-TiO2 TNAs to E.coli (a) and staphylococcus aureus (b) respectively. 空白 TiO2-NT Ag-TNA 空白 TiO2-NT Ag-TNA Fig.1 Photocatalytic degradation of methylene blue(MB) on TiO2 nanotubes and Ag-TiO2 nanotubes arrays formed by soaking in 0.5M,1M,1.5M AgNO3 for different times and subsequent photoreduction treatment.