N_乙烯基咪唑共聚交联微球的制备及其对二氯苯酚的吸附特性.pdfVIP

Vol. 23 No. 3 2010 9 Journal of Functional Polymer s 275 N 王蕊欣, 高保娇 ( 中北大学化学工程系, 太原030051) : 采用悬浮聚合法, 以N乙烯基咪唑( NVI) 为主 体苯乙烯( St) 为共 体乙二醇二甲 基丙烯酸酯( EGDMA) 为交联剂聚乙烯醇( PVA) 为分散剂, 制备了吸附材料PNVISt 交联微球 重点考察了分散剂用量搅拌速率油水两相体积比交联剂用量NaCl 用量对交联微球的成球性 能及粒度的影响规律, 研究了该微球对二氯苯酚的静态吸附性能结果表明: 分散剂用量搅拌速 率与油水两相体积比是影响交联微球制备的主要因素, 在水相中加入电解质 NaCl 有助于成球过 程, 控制悬浮聚合的反应条件, 可以制备出球形度好粒径在 100 ~ 200 m 可调控的交联微球 PNVISt 静态吸附实验结果表明: 凭借强烈的氢键相互作用, 微球表面的咪唑基团对二氯苯酚具 有很强的吸附能力, 饱和吸附量可达143 mg/ g : 聚N 乙烯基咪唑; 交联微球; 二氯苯酚; 吸附 : O 31. 5 : A : 2010) 0302750 Preparation and 2, 4Chlorophenol Adsorption Behavior of CrossLinked Polyvinylimidazole Microspheres WANG Ruixin, GAO Baojiao ( Department of Chemical Engineering, North University of China, T aiyuan 030051, China) Abstract: Crosslinked polyvinylimidazole microspheres ( PNV ISt) w ere prepared through suspension polymerization using Nvinylimidazole ( NVI) as monomer, styrene ( St) as comonomer, ethyl glycol dime thacylate ( EGDMA) as crosslinker and polyvinyl alcohol( PVA) as dispersant. Effects of various factors such as the amount of the dispersant, crosslinker and NaCl concentration, the stirring rate, the volume ratio of oil phase to w ater phase on the morphology and size of the crosslinked microspheres w ere investi gated. T he adsorption properties of microspheres PN VISt tow ards 2, 4dichlorophenol w ere studied pre liminarily. Results show that the amount of the dispersant, the stirring rate and the ratio of oil phase to w ater phase are key factors. The crosslinked copolymer microspheres PNVISt w ith excellent sphericity and controllable particle diameter in a range of 100 200 m could be obtained. In addition, the adsorpt