水再分散型纳米纤维素晶须的制备及表征.pdfVIP

第34卷第3期 林 产 化 学 与 工 业 Vol.34 No.3 2014年6月 Chemistry and Industry of Forest Products June2014 doi:10.3969/ j.issn.0253-2417.2014.03.002 水再分散型纳米纤维素晶须的制备及表征 陶向文,叶代勇* (华南理工大学化学与化工学院, 广东 广州 510640) 摘 要: 通过硫酸水解脱脂棉制备了纳米纤维素晶须(NCW)悬浮液,在NCW 悬浮液中加入一定 量阴离子型高分子电解质羧甲基纤维素钠(CMC-Na)后,喷雾干燥悬浮液制备出了粉状 NCW 固 体。 将NCW 固体重新分散于去离子水中得到再分散纳米纤维素晶须(re-NCW)悬浮液,探究了再 TAOXiang-wen 分散过程中CMC-Na 用量、超声波作用时间、NCW 悬浮液的pH值、喷雾干燥入口温度对re-NCW 再分散性能的影响,并用傅里叶红外光谱(FT-IR)、扫描电子显微镜(SEM)、透射电镜(TEM)、热失重分析(TGA)等方法 对re-NCW进行了表征。 结果表明,当CMC-Na添加量为6 %、超声波作用时间为5 min,NCW 悬浮液的pH值为7,喷雾 干燥入口温度为160 ℃时,制备的re-NCW平均粒径约为170 nm,Zeta 电位值约为65 mV,具有良好的可再分散性。 关键词: 纳米纤维素晶须;羧甲基纤维素钠;水再分散 中图分类号:TQ35 文献标识码:A 文章编号:0253-2417(2014)03-0007-06 Preparation and Characterization of Water-redispersed Nanocellulose Whiskers TAO Xiang-wen,YE Dai-yong (School of Chemistry and Chemical Engineering,South China University of Technology,Guangzhou510640,China) Abstract:Aqueoussuspensionsof nanocellulosewhiskers (NCW)werepreparedbythe sulfuricacidhydrolysis. Theredispersed powders of NCW were obtained through adding a certain amount of sodium carboxymethyl cellulose (CMC-Na) to NCW suspensions and thenprocessedby spray drying. TheNCWpowderswereredispersedinthewater andtheredispersedNCW (re- NCW)were obtained. The influences of CMC-Na dosages,ultrasonic time,pH of the suspensions,and inlet temperature of the spray drying on the redispersibility of re-NCW were investigated. Then the re-NCW were characterized using several analytical techniques such as FT-IR,SEM,TEM and TGA etc. The results showed that the NCW water-redispersibility suspensio