理想混合表面活性剂表面张力的计算公式及实验验证.pdfVIP

理化学学报(Wuli Huaxue Xuebao) 400 Acta Phys. Chim. Sin., 2008, 24(3) ：400-404 March [Article] 理想混合表面活性剂表面张力的计算公式及实验验证 国云1 王正武2, 王仲妮3 刘 峰1 肖建毅1 (1 江南大学化学与材料工程学院, 江苏无锡 214122; 2 上海交通大学农业与生 学院食品科学与工程系, 上海 200240; 3 山东师范大学化学系, 济南 250014) 摘要： 采用Newton 迭代法, 给出了两种计算二组分表面活性剂理想混合体系表面张力的显函数简捷表达式, 并通过膦氧化物同系 , 季铵盐混合体系, 以及全氟辛酸铵和全氟壬酸铵混合系列表面张力的实验值和数值解 对其精确性进行了验证. 结果表明, 两种迭代法都有很快的收敛速度, 表达式的相对误差都在1%之内. 关键词： 表面活性剂, 理想混合体系, 表面张力 中图分类号： O647.2 Theoretical Expression and Experiment on Surface Tension in Ideal Binary Mixtures of Surfactants TU Guo Yun1 WANG Zheng Wu2, WANG Zhong Ni3 LIU Feng1 XIAO Jian Yi1 1 ( School of Chemical and Material Engineering, Jiangnan University, Wuxi 214122, Jiangsu Province, P. R. China; 2Department of Food Science Technology, School of Agriculture and Biology, Shanghai Jiaotong University, Shanghai 200240, P. R. China; 3Depa rtment of Chemistry, Shandong Normal University, Jinan 250014, P. R. China) Abstract ： Two kinds of equations of the surface tension vs the concentration for ideal binary mixtures of surfactants were acquired with Newton iterative method. The accuracy could be verified by comparison among the values obtained respectively from the iterative, the numerical and observable approaches for surface tension of the ideal binary mixed homology systems C H P