甘油氢氯化制备二氯丙醇的反应特性.pdfVIP

Vol. 36 No. 5 ( ) 201010 Journal of East China University of Science an Technology ( Natural Science E ition) 617 : 2010) 1 2 2 岳 群 , 朱家文, 袁向前 ( 1. 上海氯碱化工股份有限公司, 上海200241; 2. 华东理工大学化工学院, 上海200237) : 以成本低廉 有机酸为催化剂, 以甘油氯化氢为原料, 在温和 条件下, 对制备二氯丙 醇 反应特性进行了研究在大量实验数据 基础上, 建立了不同催化剂条件下 反应动力学方 程, 考察了不同反应温度催化剂质量分数对甘油氢氯化反应 影响, 并同时进行了浓度和温度效 应 分析, 提出了最优操作温度曲线方程 : 甘油; 二氯丙醇; 反应动力学 : T Q223. 123 : A Reaction of Glycerol Hydrochiorination to Prepare Dichloropropanol 1 2 2 Y UE Qun , ZH U J iaw en , Y UA N X iangqian ( 1. Shang hai ChlorA lkal i Chemic al Co . , L d, Shang hai 200241, China; 2. S chool of Che mic al E ng inee ring , Eas China Univ e rs i y of S cie nce and Technology , Shang hai 200237, Ch ina) Abstract: The synthesis reaction of ichloropropanol from glycerol an hy rochlori e catalyze by cheap organic aci un er mil con itions w as stu ie . Base on large amount of experimental ata, the kinetic equations w ith ifferent catalysts w ere establishe . T he effects of temperature an catalyst content on the glycerol hy rochiorination w ere investigate . T he optimum operation temperature curve w as obtaine by the analysis of the effects of reactant concentration an temperature. Key words: glycerol; ichloropropanol; reaction kinetics [ 12] 1 [ 3] [ 46] , : , , , ( w ) 0. 029 , , , , 363~ 383 K, , ; , 3. 0 L/ min , 1 h, 1. 5 L/ min 2 h, 1. 0 L/ min 4 h, , 1, 3 0. 5 L/ mi