静电纺聚丙烯腈基超细碳纤维研究.pdfVIP

K27 静电纺聚丙烯腈基超细碳纤维的研究 1 1 1，2 1 唐雯 ，俞昊 ，朱美芳 ，张雯 (1.东华大学材料科学与工程学院，上海，201620；2.纤维改性国家重点实验室， 上海，201620) 摘要：由于超细碳纤维直径细且具有高导电性，在作为催化剂及催化剂载体，锂离子电池阳极 材料、双电层电容器电极、场电子发射材料等领域极具应用价值，是航天航空、国防军工尖端 技术领域必需的新材料。本论文利用静电纺丝设备，在仅改变滚筒收集装置的转速的条件下， 制得不同有序度的聚丙烯腈超细纤维毡，利用扫描电子显微镜来观察纤维的直径及形态，得出 纤维排列的有序度随滚筒转速的增加而提高。再将制得的聚丙烯腈纳米纤维毡在不同温度下预 氧化，利用差热分析来计算环化度，确定最佳的预氧化温度。最终得到280℃下，环化度接近于 1，预氧化完全。最后经过炭化，得到碳纳米纤维毡，分析在不同滚筒转速下收集的不同有序度 的碳纳米纤维毡的力学性质。通过拉伸试验，得出随着转速的增加，纤维毡的拉伸强度有所增 加。 关键词：聚丙烯腈，静电纺丝，预氧化，炭化，力学性能 THE STUDY ON PAN-BASED ULTRAFINE CARBON FIBER MADE BY ELECTRICAL SPINNING 1 1 1,2 1 Tang Wen , Yu Hao , Zhu Meifang , Zhang Wen (1. Donghua University, Shanghai, 201620, China；2. State Key Lab for Modification of Chemical Fibers and Polymer Materials, Shanghai, 201620, China) Abstract: Ultrafine carbon fibers, which have fine diameter and high electrical conductivity, have a great application in such areas as catalyst and carrier for catalyst, the anode material for lithium battery, capacitor electrode with double electrical layers and field electron transmit material and so on. This material has an application in the field of spaceflight, aviation and sophisticated technique of national defense and military. In this thesis the PAN fiber web in uniaxially aligned arrays were produced by electrospinning equipment under the condition of only different rolling speeds. The diameter and morphology of the ultrafine fibers in the PAN electrospinning fiber mats were observed by Scanning Electron microscopy (SEM).SEM images shows that the degree of ordering increased with the increasing rolling speed. And then the PAN fiber webs were pre-oxidated to different temperatures in order to find the optimal temperature. The images of DSC shows the stabili