硫酸氢钾和氢氧化钠二步法催化潲水油制备生物柴油.pdfVIP

ofAnhui 责任编辑罗芸责任校对卢瑶 安徽农业科学，Journal Agri．Sci．2009，37(14)：6317—6318，6346 硫酸氢钾和氢氧化钠二步法催化潲水油制备生物柴油 蔡新安 (景德镇高等专科学校生化系，江西景德镇333000) 摘要初步探讨了以潲水油为原料，以硫酸氢钾和氢氧化钠为催化剂，用二步法催化高酸价潲水油制备生物柴油的生产工艺。结果表 明，硫酸氢钾对酯化反应具有很强的催化活性，而且可以回收利用。通过正交试验得到最佳酯化反应条件：硫酸钾用量4％，反应温度 65～70‘=c，醇油质量比3：5，反应时间2 ℃，反应时间lh，醇油质量比1：5。经过二步催化，产品中总的脂肪酸甲酯(生物柴油)含量迭96．7％。 关键词潲水油；生物柴油；酯交换；酯化；硫酸氢钾；氢氧化钠 中图分类号S216．2文献标识码A 文章编号0517—6611(2009)14—06317—02 BiodieselfromWasteGreaseRestaurant ProcessPotassiumBisulfateandSodluln Preparing byTwo-stepCatalyzedby Hydroxide CAI of andChemical Xin,an(DepartmentBiologic Engineering，JingdezhenComprehensiveCollege，Jingdezhen，Jiangxi333000) AbstractWasterestaurantwasusedastheraw sodium usedas grease material．potassiumbisulfate(KHSOd)andhydroxide(Na0H)Was the acidvaluewasterestaurant ofbiodieselWas wasusedto the grease，the catalyst．andtwo．stepprocesses catalyzehigh productionprocess be discussedinthis resultsindicated a in alsocould study．The KHSO。hadgreatcatalyticactivityesterification。furthermore。itrecycled．The estefificationwereobtained of Was reaction was65— optimal parameters byorthogonalexperiment，thedosageKHSOd4wt％，the temperature offree acidsWas97．22％under 70oC。andthemassratioofalcoholto was3：5．thereactiontimewas2h，theesterifiablerate grease fatty theconditionabovementioned．Theofester was ofNaOHwasl reaction was parametersexchangefollowing．thedosage wt％。the temperature