三维质子交换膜燃料电池的完整模型.pdfVIP

38 9 Vo l138 N o19 2 0 0 6 9 JOURNAL OF HARBIN INSTITUTE OF TECHNOLOGY Sep. 2006 杜春雨, 史鹏飞 ( , 5000 , E-m ail: cydu@ hit. edu. cn) : 通过聚集体模型描述催化层结构, 建立了阴阳极包括蛇形流道多孔扩散层质 交换膜和催化层 的完整质 交换膜燃料电池(PEMFC)三维流体力学模型, 重点研究稳态条件下的基本工作参数分布和气体 扩散层渗透率的影响. 模型方程借助于计算流体力学软件- Fluent求解. 模拟的极化行为验证了模型的有效 性, 说明在燃料电池模型中充分考虑催化层的必要性. 计算结果表明流体流速压力反应气体组成和局部电 流密度等参数的空间分布明显, 并且受气体扩散层渗透率影响明显, 优化气体扩散层结构至关重要. : 质 交换膜燃料电池; 聚集体结构; 渗透率; 三维数学模拟; 计算流体力学 : TM9 14 : A : 0367- 6234( 2006) 09- 5 - 04 Th ree-dim ensional com p lete m ath em aticalm od el for a proton exchange m em brane fuel cell DU Chun-yu, SH I Peng-fei ( Dept. of App lied Chem istry, H arbin Institute ofT echnology, H arb in 5000 , China, E-m ai:l cydu@ h it. edu. cn) Abs tract: A computational flu id dynam ic ( CFD) model for a proton exchange membrane fuel cell ( PEM FC) w ith serpentine flow fieldsw as presented by tak ing into account the catalyst layerw ith agglom erate structures. The three- dmi ensional governing equations of continuity, momentum and species concentrations coupledm ass source/sink term sw ere solved by a CFD softw are- F luent 610, an over computational domain, wh ich consist of gas channels, gas d iffusion layers, and catalyst layers forboth the anode and the cathode asw ell as the solid polymer membrane. The modelw as validated by the good agreem ent bewt een predicted resu lts and the exper-i mental data available in the literature, demonstrating the necessity of incorporating the catalyst layer into PEM- FC models. Smi ulation resu lts also revealed that the spatial d istributions of basicw orking parameters ( gas ve- locity, s